Sodium silicate route: fabricating high monodisperse hollow silica spheres by a facile method

被引:6
作者
Wu, Weiwei [1 ]
Cao, Shunsheng [1 ]
Yuan, Xinhua [1 ]
Zhao, Zhiyuan [1 ]
Fang, Long [1 ]
机构
[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China
关键词
Sodium silicate; Hollow silica spheres; Monodispersity; A facile method; TUNABLE PORE-SIZE; MESOPOROUS SILICA; PARTICLES; POLYMER;
D O I
10.1007/s10934-011-9549-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
This paper exhibits good example of high well-defined hollow silica spheres by using a low-cost sodium silicate precursor via a facile method. The N-2 adsorption isotherm shows that this hollow structure leads to a high Brunauer-Emmett-Teller specific area of ca. 217.755 m(2) g(-1). Transmission electron microscopy and scanning electron microscopy images indicate that prepared hollow silica spheres have uniform morphology and narrow size distribution. Particle size analyzer measurement (polydispersity = 0.005; GSD = 1.073) also further confirms the fact that hollow silica spheres with high monodispersity have been successfully developed as expected.
引用
收藏
页码:913 / 919
页数:7
相关论文
共 30 条
[21]   Molecular imprinting: A versatile tool for separation, sensors and catalysis [J].
Li, Wuke ;
Li, Songjun .
OLIGOMERS POLYMER COMPOSTIES MOLECULAR IMPRINTING, 2007, 206 :191-210
[22]   Encapsulation and Ostwald ripening of Au and Au-Cl complex nanostructures in silica shells [J].
Lou, Xiong Wen ;
Yuan, Chongli ;
Rhoades, Elizabeth ;
Zhang, Qing ;
Archer, Lynden A. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (13) :1679-1684
[23]   DISPERSION POLYMERIZATION OF STYRENE IN POLAR-SOLVENTS .6. INFLUENCE OF REACTION PARAMETERS ON PARTICLE-SIZE AND MOLECULAR-WEIGHT IN POLY(N-VINYLPYRROLIDONE)-STABILIZED REACTIONS [J].
PAINE, AJ ;
LUYMES, W ;
MCNULTY, J .
MACROMOLECULES, 1990, 23 (12) :3104-3109
[24]   Synthesis of mesoporous silica with tunable pore size from sodium silicate solutions and a polyethylene oxide surfactant [J].
Sierra, L ;
Guth, JL .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 27 (2-3) :243-253
[25]   Visual and quantitative detection of copper ions using magnetic silica nanoparticles clicked on multiwalled carbon nanotubes [J].
Song, Yujun ;
Qu, Konggang ;
Xu, Can ;
Ren, Jinsong ;
Qu, Xiaogang .
CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6572-6574
[26]   Formation mechanisms of colloidal silica via sodium silicate [J].
Tsai, Ming-Shyong ;
Huang, Po Yuan ;
Yang, Chien-Hsin .
JOURNAL OF NANOPARTICLE RESEARCH, 2006, 8 (06) :943-949
[27]   One-step coating of fluoro-containing silica nanoparticles for universal generation of surface superhydrophobicity [J].
Wang, Hongxia ;
Fang, Jian ;
Cheng, Tong ;
Ding, Jie ;
Qu, Liangti ;
Dai, Liming ;
Wang, Xungai ;
Lin, Tong .
CHEMICAL COMMUNICATIONS, 2008, (07) :877-879
[28]   One-pot synthesis of nanotube-based hierarchical copper silicate hollow spheres [J].
Wang, Yongqiang ;
Wang, Guozhong ;
Wang, Hongqiang ;
Cai, Weiping ;
Zhang, Lide .
CHEMICAL COMMUNICATIONS, 2008, (48) :6555-6557
[29]   Layer-by-layer deposition of poly(diallyldimethylammonium chloride) and sodium silicate multilayers on silica-sphere-coated substrate-facile method to prepare a superhydrophobic surface [J].
Zhang, Lianbin ;
Chen, Huan ;
Sun, Junqi ;
Shen, Jiacong .
CHEMISTRY OF MATERIALS, 2007, 19 (04) :948-953
[30]   Fabrication of mesoporous silica-coated CNTs and application in size-selective protein separation [J].
Zhang, Min ;
Wu, Yipan ;
Feng, Xizeng ;
He, Xiwen ;
Chen, Langxing ;
Zhang, Yukui .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (28) :5835-5842