Two isostructural amine-functionalized 3D self-penetrating microporous MOFs exhibiting high sorption selectivity for CO2

被引：32

作者：

Liu, Bo ^{[1
]}

Zhao, Ruili ^{[1
]}

Yang, Guoping ^{[1
]}

Hou, Lei ^{[1
]}

Wang, Yao-Yu ^{[1
]}

Shi, Qi-Zhen ^{[1
]}

机构：

[1] Northwest Univ, Coll Chem & Mat Sci, Shaanxi Key Lab Physicoinorgan Chem, Key Lab Synthet & Nat Funct Mol Chem,Minist Educ, Xian 710069, Peoples R China

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 11期

关键词：

METAL-ORGANIC FRAMEWORK; GAS-ADSORPTION; CARBON-DIOXIDE; CAPTURE; SEPARATION; NETWORKS; TOPOLOGY; SITES;

D O I：

10.1039/c3ce26800d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two isostructural 3D microporous metal-organic frameworks, which show a 6-connected (4(8).6(6).8) self-penetrating net, contain two different narrow-sized channels functionalized by amino groups on the pore surface. In particular, both of them show exceptional stability and a high selectivity for CO2 over N-2 at 298 K.

引用

页码：2057 / 2060

页数：4

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