Molecule-induced homolysis of N-hydroxyphthalimide (NHPI) by peracids and dioxirane.: A new, simple, selective aerobic radical epoxidation of alkenes

被引：47
作者：
Minisci, F
Gambarotti, C
Pierini, M
Porta, O
Punta, C
Recupero, F
Lucarini, M
Mugnaini, V
机构：
[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim G Natta, I-20131 Milan, Italy
[2] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40126 Bologna, Italy
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 09期
关键词：
D O I：
10.1016/j.tetlet.2005.12.089
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Evidences are reported concerning the molecule-induced homolysis of NHPI by peracids and dioxirane; their combination can be utilized for the aerobic free-radical epoxidation of alkenes with selectivity quite different from the well-known epoxidation by peracids. (c) 2006 Elsevier Ltd. All rights reserved.
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页码：1421 / 1424
页数：4
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