Molecule-induced homolysis of N-hydroxyphthalimide (NHPI) by peracids and dioxirane.: A new, simple, selective aerobic radical epoxidation of alkenes

被引：46

作者：

Minisci, F

Gambarotti, C

Pierini, M

Porta, O

Punta, C

Recupero, F

Lucarini, M

Mugnaini, V

机构：

[1] Politecn Milan, Dipartimento Chim Mat & Ingn Chim G Natta, I-20131 Milan, Italy

[2] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40126 Bologna, Italy

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 09期

关键词：

D O I：

10.1016/j.tetlet.2005.12.089

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Evidences are reported concerning the molecule-induced homolysis of NHPI by peracids and dioxirane; their combination can be utilized for the aerobic free-radical epoxidation of alkenes with selectivity quite different from the well-known epoxidation by peracids. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1421 / 1424

页数：4

共 3 条

[1] Selective aerobic radical epoxidation of α-olefins catalyzed by N-hydroxyphthalimide (NHPI)
Punta, Carlo
Moscatelli, Davide
Porta, Ombretta
Minisci, Francesco
Recupero, Francesco
Gambarotti, Cristian
Lucarini, Marco
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
[2] A new, highly selective, free-radical aerobic oxidation of silanes to silanols catalysed by N-hydroxyphthalimide under mild conditions.
Minisci, F
Recupero, F
Punta, C
Guidarini, C
Fontana, F
Pedulli, GF
SYNLETT, 2002, (07) : 1173 - 1175
[3] A new, highly selective synthesis of aromatic aldehydes by aerobic free-radical oxidation of benzylic alcohols, catalysed by n-hydroxyphthalimide under mild conditions.: Polar and enthalpic effects
Minisci, F
Punta, C
Recupero, F
Fontana, F
Pedulli, GF
CHEMICAL COMMUNICATIONS, 2002, (07) : 688 - 689

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