Hydroarylation of unactivated olefins catalyzed by platinum(II) complexes

被引：70

作者：

McKeown, Bradley A. ^{[1
]}

Foley, Nicholas A. ^{[1
]}

Lee, John P. ^{[1
]}

Gunnoe, T. Brent ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Chem, Raleigh, NC 27695 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 16期

基金：

美国能源部;

关键词：

D O I：

10.1021/om8006008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pt(II) complex [('bpy)Pt(Ph)(THF)][BAr'(4)] catalyzes the hydroarylation of olefins utilizing unactivated substrates. Preliminary studies indicate that the reactions proceed via Pt-mediated C-H activation rather than a traditional Friedel-Crafts pathway.

引用

页码：4031 / 4033

页数：3

共 24 条

[1] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[2] Catalytic hydroarylation of olefins promoted by dicationic Platinum(II) and Palladium(II) complexes. The interplay of C-C bond formation and M-C bond cleavage [J].

Cucciolito, Maria Elena ;

D'Amora, Angela ;

Tuzi, Angela ;

Vitagliano, Aldo .

ORGANOMETALLICS, 2007, 26 (21) :5216-5223

[3] Homogeneous hydrocarbon C-H bond activation and functionalization with platinum [J].

Fekl, U ;

Goldberg, KI .

ADVANCES IN INORGANIC CHEMISTRY: INCLUDING BIOINORGANIC STUDIES, VOL 54: INORGANIC REACTION MECHANISMS, 2003, 54 :259-320

[4] Combined experimental and computational study of TpRu{P(pyr)3}(NCMe)Me (pyr = N-pyrrolyl):: Inter- and intramolecular activation of C-H bonds and the impact of sterics on catalytic hydroarylation of olefins [J].

Foley, Nicholas A. ;

Lail, Marty ;

Gunnoe, T. Brent ;

Cundari, Thomas R. ;

Boyle, Paul D. ;

Petersen, Jeffrey L. .

ORGANOMETALLICS, 2007, 26 (23) :5507-5516

[5] Comparative reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3):: Impact of ancillary ligand L on activation of carbon-hydrogen bonds including catalytic hydroarylation and hydrovinylation/oligomerization of ethylene [J].

Foley, Nicholas A. ;

Lail, Marty ;

Lee, John P. ;

Gunnoe, T. Brent ;

Cundari, Thomas R. ;

Petersen, Jeffrey L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (21) :6765-6781

[6] Efficient activation of aromatic C-H bonds for addition to C-C multiple bonds [J].

Jia, CG ;

Piao, DG ;

Oyamada, JZ ;

Lu, WJ ;

Kitamura, T ;

Fujiwara, Y .

SCIENCE, 2000, 287 (5460) :1992-1995

[7] Unexpected selectivities in C-H activations of toluene and p-xylene at cationic platinum(II) diimine complexes.: New mechanistic insight into product-determining factors [J].

Johansson, L ;

Ryan, OB ;

Romming, C ;

Tilset, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6579-6590

[8] Stoichiometric and catalytic arene activations by platinum complexes containing bidentate monoanionic nitrogen-based ligands [J].

Karshtedt, D ;

McBee, JL ;

Bell, AT ;

Tilley, TD .

ORGANOMETALLICS, 2006, 25 (07) :1801-1811

[9] Pt-Ag catalyst system for hydroarylations with unactivated arenes and olefins [J].

Karshtedt, D ;

Bell, AT ;

Tilley, TD .

ORGANOMETALLICS, 2004, 23 (18) :4169-4171

[10] Experimental and computational studies of ruthenium(II)-catalyzed addition of arene C-H bonds to olefins [J].

Lail, M ;

Bell, CM ;

Conner, D ;

Cundari, TR ;

Gunnoe, TB ;

Petersen, JL .

ORGANOMETALLICS, 2004, 23 (21) :5007-5020

← 1 2 3 →