Dynamic self-assembly in ensembles of camphor boats

被引:106
作者
Soh, Siowling
Bishop, Kyle J. M.
Grzybowski, Bartosz A. [1 ]
机构
[1] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
关键词
D O I
10.1021/jp7111457
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Millimeter-sized gel particles loaded with camphor and floating at the interface between water and air generate convective flows around them. These flows give rise to repulsive interparticle interactions, and mediate dynamic self-assembly of nonequilibrium particle formations. When the numbers of particles, N, are small, particle motions are uncorrelated. When, however, N exceeds a threshold value, particles organize into ordered lattices. The nature of hydrodynamic forces underlying these effects and the dynamics of the self-assembling system are modeled numerically using Navier-Stokes equations as well as analytically using scaling arguments.
引用
收藏
页码:10848 / 10853
页数:6
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