Effects of stearic acid on synthesis of magnesium hydroxide via direct precipitation

被引:33
作者
Yang, Yun-Feng [1 ]
Wu, Xiang-Feng [1 ]
Hu, Guo-Sheng [1 ]
Wang, Biao-Bing [1 ,2 ]
机构
[1] N Univ China, Shanxi Res Ctr Engn Technol Engn Plast, Taiyuan 030051, Peoples R China
[2] Kansas State Univ, Dept Grain Sci & Ind, Manhattan, KS 66506 USA
关键词
characterization; crystal morphology; growth from solutions; selective epitaxy;
D O I
10.1016/j.jcrysgro.2008.05.006
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Hydrophobicity magnesium hydroxide nanoneedles were synthesized via direct precipitation method by using stearic acid as surfactant, magnesium chloride hexahydrate in the presence of acetone as precursor and industrial ammonia as precipitator in this paper. The morphology, crystal phase was observed by transmission electron microscopy (TEM) and X-ray diffraction (XRD) while the thermal gravity analysis (TGA) technique was used to analyze the thermal behavior of the superfine magnesium hydroxide. The experiment results showed that the hydrophobicity of products was significantly improved and the particles with regular circular-shaped were completely turned into needle-like particles with increasing the use level of stearic acid. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:3557 / 3560
页数:4
相关论文
共 28 条
  • [1] Alexandre M, 2001, MACROMOL RAPID COMM, V22, P643, DOI 10.1002/1521-3927(20010501)22:8<643::AID-MARC643>3.0.CO
  • [2] 2-#
  • [3] The effect of high-energy electron beam irradiation and content of ATH upon mechanical and thermal properties of EVA copolymer
    Gheysari, D
    Behjat, A
    [J]. EUROPEAN POLYMER JOURNAL, 2002, 38 (06) : 1087 - 1093
  • [4] Characterization of coated particulate fillers
    Gilbert, M
    Sutherland, I
    Guest, A
    [J]. JOURNAL OF MATERIALS SCIENCE, 2000, 35 (02) : 391 - 397
  • [5] Polyethylene compounds containing mineral fillers modified by acid coatings. 2: Factors influencing mechanical properties
    Haworth, B
    Raymond, CL
    Sutherland, I
    [J]. POLYMER ENGINEERING AND SCIENCE, 2001, 41 (08) : 1345 - 1364
  • [6] Sol-gel preparation of MgO fibers
    Kordas, G
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2000, 10 (05) : 1157 - 1160
  • [7] Flow micro-calorimetry and FTIR studies on the adsorption of saturated and unsaturated carboxylic acids onto metal hydroxide flame-retardant fillers
    Liauw, CM
    Rothon, RN
    Lees, GC
    Iqbal, Z
    [J]. JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY, 2001, 15 (08) : 889 - 912
  • [8] LIEBER CM, 1996, P RA WELCH FDN 40 C, P75205
  • [9] Controlled synthesis of magnesium hydroxide nanoparticles with different morphological structures and related properties in flame retardant ethylene-vinyl acetate blends
    Lv, J
    Qiu, LZ
    Qu, BJ
    [J]. NANOTECHNOLOGY, 2004, 15 (11) : 1576 - 1581
  • [10] Controlled growth of three morphological structures of magnesium hydroxide nanoparticles by wet precipitation method
    Lv, JP
    Qiu, LZ
    Qu, BJ
    [J]. JOURNAL OF CRYSTAL GROWTH, 2004, 267 (3-4) : 676 - 684