Diverse CdII coordination complexes derived from bromide isophthalic acid binding with auxiliary N-donor ligands

被引:4
作者
Tang, Meng [1 ]
Dong, Bao-Xia [1 ]
Wu, Yi-Chen [1 ]
Yang, Fang [1 ]
Liu, Wen -Long [1 ]
Teng, Yun-Lei [1 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
关键词
Halogenated isophthalic acid; Coordination complex; Flexible; Semiflexible; Photoluminescence; METAL-ORGANIC FRAMEWORKS; 5-IODO-ISOPHTHALIC ACID; CRYSTAL-STRUCTURES; HYDROTHERMAL SYNTHESES; MAGNETIC-PROPERTIES; COEXISTENT GROUPS; POLYMERS; PHOTOLUMINESCENCE; CLUSTERS; ZN(II);
D O I
10.1016/j.jssc.2016.09.008
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination characteristics of 4-bromoisophthalic acid (4-Br-H(2)ip) have been investigated in a series of Cd-II-based frameworks. Hydrothermal reactions of Cd-II salts and 4-Br-H(2)ip together with flexible or semiflexible N-donor auxiliary ligands resulted in the formation of four three-dimensional co-ordination complexes with diverse structures: {Cd(bix)(0.5)(bix)(0.5)(4-Br-ip)]center dot H2O}(n) (1), [Cd (bbi)(0.5)(bbi)(0.5)(4-Br-ip)](n) (2), {[Cd(btx)(0.5)(4-Br-ip)(H2O)]center dot 0.5CH(3)OH center dot H2O}(n) (3) and {[Cd(bbt)(0.5)(4-Br-ip) (H2O)]center dot 3 center dot 5H(2)O}(n) (4). These compounds were characterized by elemental analyses, IR spectra, single crystal and powder X-ray diffraction. They displayed diverse structures depending on the configuration of the 4-connected metal node, the coordination mode of the 4-Br-H(2)ip, the coordination ability and conformationally flexibility of the N-donor auxiliary. Compound 1 exhibits 3-fold interpenetrated 6(6) topology and compound 2 has a 4(12) topology. Compounds 3-4 have similar 3D pillar-layered structures based on 3,4-connected binodal net with the Schlafli symbol of (4-3(8)). The thermal stabilities and photoluminescence properties of them were discussed in detail. (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码:12 / 19
页数:8
相关论文
共 45 条
[1]  
Batten SR, 2009, COORDINATION POLYMERS: DESIGN, ANALYSIS AND APPLICATION, P1, DOI 10.1039/9781847558862
[2]   Organization of Mn-Clusters in pcu and bcu Networks: Synthesis, Structure, and Properties [J].
Bhattacharya, Saurav ;
Gnanavel, M. ;
Bhattacharyya, Aninda J. ;
Natarajan, Srinivasan .
CRYSTAL GROWTH & DESIGN, 2014, 14 (01) :310-325
[3]   Co(II)/Zn(II) Coordination Polymers with Angular Dicarboxylate and Flexible N-Donor Struts: Structural and Photoluminescence Studies [J].
Bisht, Kamal Kumar ;
Suresh, Eringathodi .
CRYSTAL GROWTH & DESIGN, 2013, 13 (02) :664-670
[4]   Polycatenation, polythreading and polyknotting in coordination network chemistry [J].
Carlucci, L ;
Ciani, G ;
Proserpio, DM .
COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :247-289
[5]   Poly[[(mu(2)- benzene-1,3-dicarboxylato){mu(2)-,4- bis[(1H- imidazol- 1- yl) methyl]benzene} cadmium] dimethylformamide monosolvate] [J].
Chen, Yan ;
Wang, Daguang ;
He, Liang ;
Li, Wei ;
Suo, Jian .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 :M616-+
[6]   Preparation, structural diversity and characterization of a family of Cd(II)-organic frameworks [J].
Deng, Ye ;
Hou, Chuan-Tao ;
Walton, Richard I. ;
Tang, Jiaqian ;
Zhu, Peizhi ;
Zhang, Kou-Lin ;
Ng, Seik Weng .
DALTON TRANSACTIONS, 2013, 42 (34) :12468-12480
[7]   The first tritopic bridging ligand 1,3,5-tris-(4-carboxyphenyl)-benzene (H3BTB) functionalized porous polyoxometalate-based metal-organic framework (POMOF): from design, synthesis to electrocatalytic properties [J].
Dong, Bao-Xia ;
Chen, Lu ;
Zhang, Shi-Yang ;
Ge, Jun ;
Song, Liang ;
Tian, Hui ;
Teng, Yun-Lei ;
Liu, Wen-Long .
DALTON TRANSACTIONS, 2015, 44 (03) :1435-1440
[8]   Investigation of Flexible Organic Ligands in the Molybdate System: Delicate Influence of a Peripheral Cluster Environment on the Isopolymolybdate Frameworks [J].
Dong, Bao-xia ;
Xu, Qiang .
INORGANIC CHEMISTRY, 2009, 48 (13) :5861-5873
[9]   Seven Copper Coordination Polymers Based on 5-Iodo-Isophthalic Acid: Halogen-Related Bonding and N-Donor Auxiliary Ligands Modulating Effect [J].
Dong, Ming-Ming ;
He, Lu-Lu ;
Fan, Ya-Juan ;
Zang, Shuang-Quan ;
Hou, Hong-Wei ;
Mak, Thomas C. W. .
CRYSTAL GROWTH & DESIGN, 2013, 13 (08) :3353-3364
[10]   The Chemistry and Applications of Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Cordova, Kyle E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2013, 341 (6149) :974-+