Energetic Ethylene- and Propylene-Bridged Bis(nitroiminotetrazolate) Salts

被引:48
作者
Joo, Young-Hyuk [1 ]
Shreeve, Jean'ne M. [1 ]
机构
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
关键词
energetic salts; heats of formation; nitrogen; nitrogen heterocycles; tetrazoles; NITROGEN-RICH SALTS; DERIVATIVES; PRECURSORS;
D O I
10.1002/chem.200802326
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis and detonation properties of high energy density materials with ethylene- and propylene bis(nitroiminotetrazolate) as the anions are reported; all salts were fully characterized by I R, and H-1, C-13, and N-15 NMR spectroscopy as well as elemental analyses. In addition, the heats of formation (Delta H-f) were calculated with the Gaussian 3.0 suite of programs. By using the experimental values for the densities of the nitroiminotetrazolate salts, the detonation pressures (P) and velocities (D) were calculated using Cheetah 5.0.
引用
收藏
页码:3198 / 3203
页数:6
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