Dispersible and discrete metalloporphyrin-based CMP nanoparticles enabling colorimetric detection and quantitation of gaseous SO2

被引:77
作者
Wu, Keyi [1 ]
Guo, Jia [1 ]
Wang, Changchun [1 ]
机构
[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China
关键词
CONJUGATED MICROPOROUS POLYMERS; SULFUR-DIOXIDE; FRAMEWORKS; NANOCRYSTALS; SENSITIVITY;
D O I
10.1039/c3cc47234e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metalloporphyrin-based CMP nanoparticles synthesized by the oxidative dimerization of terminal alkynes in the toluene-in-water miniemulsion possess native porosity, outstanding solution processability and uniform nanosized distribution. Also, they exhibit the sensitive color-switching ability for quantitative assay of gaseous SO2 by the noncovalent complex-displacement reaction at liquid-solid or gas-solid interfaces.
引用
收藏
页码:695 / 697
页数:3
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