Ferrocene-based aminophosphine ligands in the Ru(II)-catalysed asymmetric hydrogenation of ketones: assessment of the relative importance of planar versus carbon-centred chirality

被引：27
作者：
Chen, Weiping [1 ]
Mbafor, William [1 ]
Roberts, Stanley M. [1 ]
Whittall, John [1 ]
机构：
[1] Univ Liverpool, Dept Chem, StylaCats Ltd, Liverpool L69 7ZD, Merseyside, England
来源：
TETRAHEDRON-ASYMMETRY | 2006年 / 17卷 / 08期
关键词：
D O I：
10.1016/j.tetasy.2006.04.033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several ferrocene-based aminophosphine ligands have been prepared and shown to be effective in the Ru(II)-catalysed asymmetric hydrogenation of ketones. The enantioselectivity is mainly determined by the carbon-centred chirality of the ligands but the planar chirality is also important such that (R-C,S-FC)- or (S-C,R-FC)- are the matched chiralities. (c) 2006 Elsevier Ltd. All rights reserved.
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页码：1161 / 1164
页数：4
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