Possibilities of adiabatic precision calorimetry for kinetic evaluations

被引:2
|
作者
Heldt, K
Anderson, HL
机构
来源
JOURNAL OF THERMAL ANALYSIS | 1996年 / 47卷 / 02期
关键词
adiabatic calorimetry; kinetic evaluation; sodium thiosulphate; software;
D O I
10.1007/BF01983997
中图分类号
O414.1 [热力学];
学科分类号
摘要
The investigation of the hazardous potential of reaction courses is very important for the chemical industry. Compared with the isoperibolic the adiabatic calorimetry has essential advantages for kinetic evaluations, because corrections of heat flux are not necessary. With the adiabatic precision calorimeter ACTRON 5 is the investigation of reaction courses in small volumes possible. The possibilities of the nonlinear investigation program TA-kin are shown with examples of Semi-Batch-Measurements. With this program the change in heat capacities whilst encoring the second component is included.
引用
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页码:559 / 567
页数:9
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