Comparison of purification methods for biodiesel

被引:273
作者
Berrios, M. [1 ]
Skelton, R. L. [2 ]
机构
[1] Univ Cordoba, Dept Inorgan Chem & Chem Engn, E-14071 Cordoba, Spain
[2] Univ Cambridge, Dept Chem Engn, Cambridge CB2 3RA, England
关键词
Biodiesel; Purification; Ion exchange resin; Magnesium silicate; Glycerol; Methanol; Soap content;
D O I
10.1016/j.cej.2008.07.019
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In order to meet the very high purity requirements laid down on the European Standard for biodiesel fuel (EN 14214), a significant amount of post transesterification purification is needed. Until recently the preferred method was water washing but considerable interest is now being shown in purification by ion exchange resins and the use of magnesium silicate as a solid adsorbent. The three methods have been tested under several reaction conditions (temperature, concentration, agitation rate, etc.) in order to compare which gives better results, It has been found that it is necessary a previous methanol removal to avoid the saturation of the adsorbents. Glycerol and soap content have been removed in all the processes. Not many differences have been found on the other tested parameters, (c) 2008 Elsevier BY. All rights reserved.
引用
收藏
页码:459 / 465
页数:7
相关论文
共 10 条
[1]  
Canakci M, 2001, T ASAE, V44, P1429, DOI 10.13031/2013.7010
[2]  
COOKE BS, 2003, Patent No. 0509959
[3]   Importance of biodiesel as transportation fuel [J].
Demirbas, Ayhan .
ENERGY POLICY, 2007, 35 (09) :4661-4670
[4]   VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].
FREEDMAN, B ;
PRYDE, EH ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643
[5]   Possible methods for biodiesel production [J].
Marchetti, J. M. ;
Miguel, V. U. ;
Errazu, A. F. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2007, 11 (06) :1300-1311
[6]   Prediction of water solubility in biodiesel with the CPA equation of state [J].
Oliveira, M. B. ;
Varanda, F. R. ;
Marrucho, I. M. ;
Queimada, A. J. ;
Coutinho, J. A. P. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (12) :4278-4285
[7]  
Reid EE, 1911, AM CHEM J, V45, P479
[8]  
SKELTON RL, 2005, P 7 WORLD C CHEM ENG
[9]  
Van Gerpen J, 2004, NREL/SR-510-36240
[10]   Optimisation of integrated biodiesel production.: Part I.: A study of the biodiesel purity and yield [J].
Vicente, Gemma ;
Martinez, Mercedes ;
Aracil, Jose .
BIORESOURCE TECHNOLOGY, 2007, 98 (09) :1724-1733