To synthesize Au nanorods without the use of seed crystals, we applied gamma-ray irradiation from Co-60 radioactive source to reduce aqueous solution containing Au ions. The total dose was fixed to 6.0 kGy with various dose rates from 0.4 to 13.6 kGy/h. After the irradiation, two surface plasmon bands in the range around 530nm and above 700nm were observed in UV/vis spectra. We observed by a transmission electron microscopy (TEM) that rod-shaped Au nanoparticles with the length of 20-25 nm, and the width of about 7-15nm were produced as well as a small amount of spherical particles. The size and the aspect ratio of the Au nanorods are well correlated with gamma-ray irradiation dose rate; with increasing the dose rate, their size decreases and the aspect ratio increases. (C) 2012 The Japan Society of Applied Physics
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Soongsil Univ, Dept Phys, Seoul 06978, South KoreaSoongsil Univ, Dept Phys, Seoul 06978, South Korea
Lim, Junhwi
Na, Ye-Eun
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Soongsil Univ, Dept Phys, Seoul 06978, South KoreaSoongsil Univ, Dept Phys, Seoul 06978, South Korea
Na, Ye-Eun
Lee, Y. S.
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Soongsil Univ, Dept Phys, Seoul 06978, South KoreaSoongsil Univ, Dept Phys, Seoul 06978, South Korea
Lee, Y. S.
Bu, Sang Don
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Chonbuk Natl Univ, Dept Phys, Jeonju 54896, South Korea
Chonbuk Natl Univ, Res Inst Phys & Chem, Jeonju 54896, South KoreaSoongsil Univ, Dept Phys, Seoul 06978, South Korea