Tris(4-methoxylphenyl)phosphine-Catalyzed C-C Bond Formation Reaction: Mutual Addition of Aromatic Aldehydes and Ethyl Acrylate

被引:3
|
作者
Teng, Jun-Jiang [1 ]
Qiao, Yan-Hui [1 ]
Zhang, Qing [1 ]
Li, Chun-Hai [1 ]
Huang, Min [1 ]
机构
[1] Guangdong Univ Petrochem Technol, Sch Chem & Life Sci, Maoming 525000, Peoples R China
关键词
C-C bond formation; mutual addition; tris(4-methoxylphenyl)phosphine; INTRAMOLECULAR STETTER REACTION; CATALYTIC ASYMMETRIC-SYNTHESIS; TRIPHENYLPHOSPHINE; AZODICARBOXYLATE; THIAZOLIUM; ALLENES; DIALKYL; ESTERS; ACID;
D O I
10.1080/00397911.2011.610551
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A highly efficient intermolecular mutual addition of aromatic aldehydes with ethyl acrylate was developed by using tris(4-methoxylphenyl)phosphine as the catalyst. The reaction corresponds to the construction of 1,4-dicarbonyl compound and allylic alcohol fragments, which also provides a new way to form C-C bond.
引用
收藏
页码:848 / 858
页数:11
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