Ultrasound-assisted extraction and in situ derivatization

被引:24
作者
Delgado-Povedano, M. M. [1 ,2 ]
Luque de Castro, M. D. [1 ,2 ]
机构
[1] Univ Cordoba, Dept Analyt Chem, E-14071 Cordoba, Spain
[2] Univ Cordoba, Reina Sofia Hosp, Maimonides Inst Biomed Res IMIBIC, E-14071 Cordoba, Spain
关键词
Ultrasound-assisted solid-liquid extraction; Ultrasound-assisted liquid-liquid extraction; Ultrasound-assisted derivatization; Ultrasound-assisted emulsification-extraction; PERFORMANCE LIQUID-CHROMATOGRAPHY; ATOMIC-ABSORPTION-SPECTROMETRY; ENVIRONMENTAL WATER SAMPLES; EMULSIFICATION-MICROEXTRACTION; PRECOLUMN DERIVATIZATION; FLUORESCENCE DETECTION; PHENOLIC-COMPOUNDS; TRACE AMOUNTS; IONIC LIQUID; LIGANDLESS;
D O I
10.1016/j.chroma.2013.04.004
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Ultrasound (US) is a type of energy of growing interest for analytical chemists. The favorable effect of US on mass transfer between two phases in the same or different state has been widely demonstrated as did the number of chemical reactions accelerated/improved under ultrasonic influence. The action of US on both mass transfer and chemical reaction developed in a simultaneous manner results in a synergistic effect as a consequence of the "removal" of the target extracted species by conversion into a product. Both US-assisted solid-liquid extraction and liquid-liquid extraction have been developed with in situ derivatization at the meso- and microscale and the advantages involved in their implementation are discussed in this article. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:226 / 234
页数:9
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