Amberlite XAD7 resin functionalized with crown ether and Fe(III) used for arsenic removal from water

Water represents an essential resource for life and for all natural processes. Our existence and our economic activities are totally dependent on this precious resource. It is well known that into the developing countries the main resource of drinkable water is represented by underground waters, so their contamination with arsenic represents a real problem that needs to be solved. To solve the problem of arsenic water pollution, it was necessary to develop a series of chemical, physicochemical and biological methods to reduce arsenic concentrations from water. From all these methods, adsorption offers many advantages including simple and stable operation, easy handling of waste, absence of added reagents, compact facilities and generally lower operation cost. The goal of this paper is to study the sorption properties of a new adsorbent material prepared by impregnating Amberlite XAD7 resin with crown ether (dibenzo-18-crown-6 ether) and loaded with Fe(III) ions. Solvent impregnated resin (SIR) method was used for functionalization. Amberlite XAD7 resin functionalization was evidenced by energy dispersive X-ray analysis, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis and determination of specific surface by the Brunauer, Emmett and Teller (BET) analysis. Equilibrium, kinetic and thermodynamic studies were performed in order to determine the removal efficiency of the studied adsorbent for arsenic removal from water. In order to study the As(V) adsorption mechanism the experimental data were modelled using pseudo-first-order and pseudo-second order kinetic models. Kinetic of adsorption process was better described by pseudo-second-order model. Experimental data were fitted with three non-linear adsorption isotherm models: Langmuir, Freundlich and Sips. Obtained experimental data were better fitted by Sips adsorption isotherm. The values of thermodynamic parameters (Delta G degrees,Delta H degrees,Delta S degrees) showed that the adsorption process was endothermic and spontaneous. The results proved that Amberlite XAD7 resin with crown ether and loaded with Fe(III) is an efficient adsorbent for the As(V) removal from water. The possibility of reuse the adsorbent material through adsorption and desorption cycles was also studied and it was found that the material can be used in five sorption-desorption cycles. Maximum adsorption capacity obtained experimentally being 18.8 mu g As(V)/g material.