Precise synthesis of olefin block copolymers using a syndiospecific living polymerization system

被引：9

作者：

Cai, Zheng-guo ^{[1
]}

Su, Hai-hui ^{[1
]}

Shiono, Takeshi ^{[2
]}

机构：

[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China

[2] Hiroshima Univ, Grad Sch Engn, Higashihiroshima 7398527, Japan

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 2013年 / 31卷 / 04期

关键词：

Single-site catalyst; Propylene; Norbornene; Living polymerization; Block copolymer; ANSA-FLUORENYLAMIDODIMETHYLTITANIUM COMPLEX; STEREOBLOCK POLYPROPYLENE; METALLOCENE CATALYSTS; HIGHER; 1-ALKENE; PROPENE; NORBORNENE; PROPYLENE; CHEMISTRY;

D O I：

10.1007/s10118-013-1250-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This feature article summarizes the synthesis of novel olefin block copolymers using fast syndiospecific living homo- and copolymerization of propylene, higher 1-alkene, and norbornene with ansa-fluorenylamidodimethyltitaniumbased catalyst according to the authors' recent results. The catalytic synthesis of monodisperse polyolefin and olefin block copolymer was also described using this living system.

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页码：541 / 549

页数：9

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