Syntheses and structures of three new coordination polymers with the flexible 1,4-bis(imidazol-1-yl)butane ligand

被引：6

作者：

Liu, Kui ^{[1
]}

Zhang, Yu-Mei ^{[1
]}

Yang, Yuan ^{[1
]}

Li, Bao-Long ^{[1
,2
]}

Zhang, Yong ^{[1
]}

机构：

[1] Suzhou Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem & Chem Engn, Suzhou 215123, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 18期

关键词：

cobalt complex; copper complex bis(imidazol-1-yl)butane; crystal structure; coordination polymer;

D O I：

10.1080/00958970801989894

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new coordination polymers [Co(bimb)(2)(NCS)(2)](n) (1). {[Co(bimb)(2)(dca)(2)]center dot CH3CN}(n) (2) and [Cu(bimb)(2)(NO3)(2)](n) (3) (bimb=1,4-bis(imidazol-1-yl)butane, dca=dicyanamide) were synthesized and characterized. In 1, each Co(II) links two Co(II)'s by double bimb ligands and extends to form a one-dimensional chain containing the CO2(bimb)(2) 22-membered metallocycle. 2 and 3 are two-dimensional (4,4) networks linked by bimb bridges. The conformations of the bimb ligands in 1, 2 and 3 are analyzed.

引用

页码：2926 / 2934

页数：9

共 30 条

[1] Anion-dependence of the polymeric structures of manganese(II) complexes of N,N′-butylenebis(imidazole) [J].