Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron-Corrole Complexes: Synthesis of a Crystalline Copolymer

被引：127

作者：

Nakano, Koji ^{[1
]}

Kobayashi, Kazuki ^{[2
]}

Ohkawara, Takahiro ^{[2
]}

Imoto, Hideyuki ^{[2
]}

Nozaki, Kyoko ^{[2
]}

机构：

[1] Tokyo Univ Agr & Technol, Dept Organ & Polymer Mat Chem, Koganei, Tokyo 1848588, Japan

[2] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 23期

基金：

日本学术振兴会;

关键词：

DOUBLE METAL CYANIDES; ALLYL GLYCIDYL ETHER; ALTERNATING COPOLYMERIZATION; CYCLOHEXENE OXIDE; PROPYLENE-OXIDE; STRUCTURAL-CHARACTERIZATION; POLY(PROPYLENE OXIDE); MECHANISTIC ASPECTS; MILD CONDITIONS; BOND FORMATION;

D O I：

10.1021/ja4028633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iron-corrole complexes were found to copolymerize epoxides with CO2. The first iron-catalyzed propylene oxide/CO2 copolymerization has been accomplished. Moreover, the glycidyl phenyl ether (GPE)/CO2 copolymerization with this catalyst provided a crystalline material as a result of the isotactic poly(GPE) moiety.

引用

页码：8456 / 8459

页数：4

共 60 条

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