Radical cyclization reactions with a zirconocene-olefin complex as an efficient single electron transfer reagent

被引：0

作者：

Fujita, K ^{[1
]}

Yorimitsu, H ^{[1
]}

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mat Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

SYNLETT | 2002年 / 02期

关键词：

cyclizations; electron transfer; halo acetals; radical reactions; zirconocene-olefin complex;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A zirconocene-olefin complex induced reductive radical cyclization of beta-haloalkyl allyl acetals in THF. This complex served as a single electron transfer reagent to promote the cyclization. Furthermore, the reaction in DME afforded tetrahydrofuranylmethylzirconium species effectively.

引用

页码：337 / 339

页数：3

共 16 条

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