Synthesis, Crystal Structure, and Physical Property of Sterically Unprotected Thiophene/Phenylene Co-Oligomer Radical Cations: A Conductive π-π Bonded Supermolecular meso-Helix

被引：14

作者：

Chen, Xiaoyu ^{[1
]}

Ma, Binbin ^{[1
]}

Chen, Shuang ^{[2
]}

Li, Yizhi ^{[1
]}

Huang, Wei ^{[1
]}

Ma, Jing ^{[2
]}

Wang, Xinping ^{[1
]}

机构：

[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[2] Nanjing Univ, Theoret & Computat Chem Inst, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2013年 / 8卷 / 01期

基金：

中国国家自然科学基金;

关键词：

cations; conductivity; oligomers; radicals; thiophene; ROOM-TEMPERATURE; DNA-MOLECULES; POLYMERS; ANIONS; DIMERS; 3,4-DIBUTYL-2,5-DIPHENYL-2,25,2-TERTHIOPHENE; OLIGOTHIOPHENES; EMISSION; MONOMERS; STACKS;

D O I：

10.1002/asia.201200819

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sterically unprotected thiophene/phenylene co-oligomer radical cation salts BPnT(center dot+)[Al(ORF)(4)](-) (ORF=OC(CF3)(3), n=1-3) have been successfully synthesized. These newly synthesized salts have been characterized by UV/Vis-NIR absorption and EPR spectroscopy, and single-crystal X-ray diffraction analysis. Their conductivity increases with chain length. The formed meso-helical stacking by cross-overlapping radical cations of BP2T(center dot+) is distinct from previously reported face-to-face overlaps of sterically protected (co-)oligomer radical cations.

引用

页码：238 / 243

页数：6

共 56 条

[1]

[Anonymous], ANGEW CHEM

[2]

[Anonymous], 1995, ANGEW CHEM, V107, P2417

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