The role of KCl in cationic Gemini viscoelastic surfactant based clean fracturing fluids

被引:25
|
作者
Yang, Xiaojiang [1 ]
Mao, Jinhua [1 ]
Mao, Jincheng [1 ]
Jiang, Qihui [2 ]
Fu, Meitao [3 ]
Lin, Chong [1 ]
Chen, An [1 ]
Cun, Meng [1 ]
Du, Anqi [1 ]
Xiao, Shuyue [1 ]
Zhao, Jinzhou [1 ]
机构
[1] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
[2] CNPC Engn Technol R&D Co Ltd, Beijing 102206, Peoples R China
[3] Xian Shiyou Univ, Coll Petr Engn, Xian 710065, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Clean fracturing fluid; Cationic VES; Clay stabilizer; Anti-swelling rate; Antagonistic effects; TEMPERATURE; VES;
D O I
10.1016/j.colsurfa.2020.125510
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
KCl, as a kind of counter-ion salt, is often used in cationic viscoelastic surfactant (VES) clean fracturing fluid systems. The interaction between Cl- and VES cationic hydrophilic groups is used to promote the formation of VES micelles, which significantly improves the viscoelasticity, temperature resistance, and shear resistance of cationic VES fracturing fluid. At the same time, KCl is also a widely used inorganic salt clay stabilizer. K+ enters the interlayer of the clay and reduces the hydration expansion of clay by charge attraction. To determine whether Cl- and K+ in KCl can simultaneously play the role of counter-ion and clay stabilizer, we have evaluated the performance of KCl on viscoelasticity, temperature, shear resistance of cationic VES fracturing fluid and clay stability. The interaction of KCl and VES in clay stability was also studied. Results revealed that VES thickener has a clay stabilization effect in cationic VES fracturing fluid system, and the higher the concentration, the better the clay stabilization effect. KCl can not only effectively enhance the viscoelasticity and temperature resistance of cationic VES fracturing fluid, showing a counter-ion performance, but also acted as a clay stabilizer. However, VES and KCl can restrain each other in clay stability and produce antagonistic effects.
引用
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页数:8
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