Investigation of a Tandem Iminium Ion Allylation Approach to Piperidines

被引：8

作者：

Mancey, Nicole C. ^{[1
]}

Butlin, Roger J. ^{[1
]}

Harrity, Joseph P. A. ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

SYNLETT | 2008年 / 17期

基金：

英国工程与自然科学研究理事会;

关键词：

allylsilane; iminium ion; piperidines; annulation; Lewis acid;

D O I：

10.1055/s-0028-1083525

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A [3+3] -annulation approach to piperidines via a tandem iminium ion allylation reaction of bisaminals has been developed. The scope of this process is described as well as preliminary experiments aimed at understanding the mechanism of a competing olefin isomer formation.

引用

页码：2647 / 2650

页数：4

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