Crystal structure of a new quasi-two-dimensional compound containing 1,4-bis(imidazol-1-ylmethyl)benzene (bix) and MnII ions

被引：35
|
作者：
Shen, HY
Liao, DZ [1 ]
Jiang, ZH
Yan, SP
Wang, GL
Yao, XK
Wang, HG
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[3] Nankai Univ, Cent Lab, Tianjin 300071, Peoples R China
来源：
ACTA CHEMICA SCANDINAVICA | 1999年 / 53卷 / 06期
关键词：
D O I：
10.3891/acta.chem.scand.53-0387
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A novel Mn-II complex Mn(bix)(3)(NO2)(2). 4H(2)O [bix = 1, 4-bis(imidazol-1-yl methyl)benzene] has been synthesized and characterized by X-ray single crystal structure analysis. The complex crystallizes in the P (1) over bar space group, with lattice parameters a = 9.037(2), b = 11.498(2), c = 12.404(2) Angstrom, alpha = 110.09(3), beta = 109.62(3), gamma = 93.05(3)degrees, V = 1119(1) Angstrom(3), D-c = 1.385 Mg m(-3), Z = 1, R-1 = 0.072, wR(2) = 0.0725. The X-ray analysis shows that it is a quasi-two-dimensional network containing hydrogen bonds, terminal and bridging bix ligands concurrently.
引用
收藏
页码：387 / 390
页数：4
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