PVDF/graphene composite nanofibers with enhanced piezoelectric performance for development of robust nanogenerators

被引:273
作者
Abolhasani, Mohammad Mahdi [1 ]
Shirvanimoghaddam, Kamyar [2 ]
Naebe, Minoo [2 ]
机构
[1] Univ Kashan, Dept Chem Engn, Kashan, Iran
[2] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
基金
美国国家科学基金会;
关键词
PVDF; Graphene; Electrospinning; Nanocomposite; Electrical power generator; Energy harvesting; Piezoelectricity; POLY(VINYLIDENE FLUORIDE); PVDF; ENERGY; POLYMORPHISM; BEHAVIOR; ARRAYS; OXIDE;
D O I
10.1016/j.compscitech.2016.11.017
中图分类号
TB33 [复合材料];
学科分类号
摘要
Graphene reinforced Poly(vinylidene fluoride) composite nanofibers were prepared and their morphology, crystallinity, polymorphism and electrical outputs were investigated for the first time. Nanofibers were prepared using electrospinning technique with different graphene contents. DSC, FTIR and WAXD analyses were used to evaluate the polymorphism of PVDF crystals upon graphene addition. It was observed that addition of a small amount of graphene (0.1%wt) significantly increased the F(beta) and open-circuit voltage of nanofibers. However, further increase in graphene content decreased the electrical output of randomly oriented nanofibers. The developed PVDF/graphene nanogenerator has the ability to fully synchronize the finger movement and its generated electricity can light up a commercial LED for 30 s. This new type of PVDF generator has the potential to be used as a self-charging power source and could be used in powering the personal electronics. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:49 / 56
页数:8
相关论文
共 52 条
[11]  
Bin Y., 2015, NAN IEEE NAN 2015 IE, P932
[12]   Sound-Driven Piezoelectric Nanowire-Based Nanogenerators [J].
Cha, Seung Nam ;
Seo, Ju-Seok ;
Kim, Seong Min ;
Kim, Hyun Jin ;
Park, Young Jun ;
Kim, Sang-Woo ;
Kim, Jong Min .
ADVANCED MATERIALS, 2010, 22 (42) :4726-+
[13]   Porous PVDF As Effective Sonic Wave Driven Nanogenerators [J].
Cha, SeungNam ;
Kim, Seong Min ;
Kim, HyunJin ;
Ku, JiYeon ;
Sohn, Jung Inn ;
Park, Young Jun ;
Song, Byong Gwon ;
Jung, Myoung Hoon ;
Lee, Eun Kyung ;
Choi, Byoung Lyong ;
Park, Jong Jin ;
Wang, Zhong Lin ;
Kim, Jong Min ;
Kim, Kinam .
NANO LETTERS, 2011, 11 (12) :5142-5147
[14]   Direct-Write Piezoelectric Polymeric Nanogenerator with High Energy Conversion Efficiency [J].
Chang, Chieh ;
Tran, Van H. ;
Wang, Junbo ;
Fuh, Yiin-Kuen ;
Lin, Liwei .
NANO LETTERS, 2010, 10 (02) :726-731
[15]   Fully Rollable Transparent Nanogenerators Based on Graphene Electrodes [J].
Choi, Dukhyun ;
Choi, Min-Yeol ;
Choi, Won Mook ;
Shin, Hyeon-Jin ;
Park, Hyun-Kyu ;
Seo, Ju-Seok ;
Park, Jongbong ;
Yoon, Seon-Mi ;
Chae, Seung Jin ;
Lee, Young Hee ;
Kim, Sang-Woo ;
Choi, Jae-Young ;
Lee, Sang Yoon ;
Kim, Jong Min .
ADVANCED MATERIALS, 2010, 22 (19) :2187-+
[16]   Enhanced piezoresponse of electrospun PVDF mats with a touch of nickel chloride hexahydrate salt [J].
Dhakras, Dipti ;
Borkar, Vivek ;
Ogale, Satishchandra ;
Jog, Jyoti .
NANOSCALE, 2012, 4 (03) :752-756
[17]   Piezoelectric β-polymorph formation and properties enhancement in graphene oxide - PVDF nanocomposite films [J].
El Achaby, M. ;
Arrakhiz, F. Z. ;
Vaudreuil, S. ;
Essassi, E. M. ;
Qaiss, A. .
APPLIED SURFACE SCIENCE, 2012, 258 (19) :7668-7677
[18]   Electrical power generator from randomly oriented electrospun poly(vinylidene fluoride) nanofibre membranes [J].
Fang, Jian ;
Wang, Xungai ;
Lin, Tong .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (30) :11088-11091
[19]   Hybrid Nanogenerator for Concurrently Harvesting Biomechanical and Biochemical Energy [J].
Hansen, Benjamin J. ;
Liu, Ying ;
Yang, Rusen ;
Wang, Zhong Lin .
ACS NANO, 2010, 4 (07) :3647-3652
[20]   Piezoelectric properties of poly(vinylidene fluoride) and carbon nanotube blends: β-phase development [J].
Kim, Gwang Ho ;
Hong, Soon Man ;
Seo, Yongsok .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (44) :10506-10512