PVDF/graphene composite nanofibers with enhanced piezoelectric performance for development of robust nanogenerators

被引:273
作者
Abolhasani, Mohammad Mahdi [1 ]
Shirvanimoghaddam, Kamyar [2 ]
Naebe, Minoo [2 ]
机构
[1] Univ Kashan, Dept Chem Engn, Kashan, Iran
[2] Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
基金
美国国家科学基金会;
关键词
PVDF; Graphene; Electrospinning; Nanocomposite; Electrical power generator; Energy harvesting; Piezoelectricity; POLY(VINYLIDENE FLUORIDE); PVDF; ENERGY; POLYMORPHISM; BEHAVIOR; ARRAYS; OXIDE;
D O I
10.1016/j.compscitech.2016.11.017
中图分类号
TB33 [复合材料];
学科分类号
摘要
Graphene reinforced Poly(vinylidene fluoride) composite nanofibers were prepared and their morphology, crystallinity, polymorphism and electrical outputs were investigated for the first time. Nanofibers were prepared using electrospinning technique with different graphene contents. DSC, FTIR and WAXD analyses were used to evaluate the polymorphism of PVDF crystals upon graphene addition. It was observed that addition of a small amount of graphene (0.1%wt) significantly increased the F(beta) and open-circuit voltage of nanofibers. However, further increase in graphene content decreased the electrical output of randomly oriented nanofibers. The developed PVDF/graphene nanogenerator has the ability to fully synchronize the finger movement and its generated electricity can light up a commercial LED for 30 s. This new type of PVDF generator has the potential to be used as a self-charging power source and could be used in powering the personal electronics. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:49 / 56
页数:8
相关论文
共 52 条
[1]   Crystalline polymorph transition in poly(vinylidene fluoride) (PVDF)/acrylic rubber(ACM)/clay partially miscible hybrid [J].
Abolhasani, Mohammad Mahdi ;
Fashandi, Hossein ;
Naebe, Minoo .
POLYMER BULLETIN, 2016, 73 (01) :65-73
[2]   A facile method to enhance ferroelectric properties in PVDF nanocomposites [J].
Abolhasani, Mohammad Mahdi ;
Zarejousheghani, Fatemeh ;
Cheng, Zhenxiang ;
Naebe, Minoo .
RSC ADVANCES, 2015, 5 (29) :22471-22479
[3]   Different thermal analysis technique application in determination of fold surface-free energy [J].
Abolhasani, Mohammad Mahdi ;
Abadchi, Majid Rezaei ;
Magniez, Kevin ;
Guo, Qipeng .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2015, 119 (01) :527-536
[4]   CRYSTALLINE STRUCTURES AND α → β AND γ POLYMORPHS TRANSFORMATION INDUCED BY NANOCLAY IN PVDF-BASED NANOCOMPOSITE [J].
Abolhasani, Mohammad Mahdi ;
Naebe, Minoo ;
Jalali-Arani, Azam ;
Guo, Qipeng .
NANO, 2014, 9 (06)
[5]   A new approach for mechanisms of ferroelectric crystalline phase formation in PVDF nanocomposites [J].
Abolhasani, Mohammad Mahdi ;
Naebe, Minoo ;
Guo, Qipeng .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (22) :10679-10687
[6]   Evaluation of piezoelectric property of reduced graphene oxide (rGO)-poly(vinylidene fluoride) nanocomposites [J].
Alamusi ;
Xue, JunMin ;
Wu, LiangKe ;
Hu, Ning ;
Qiu, Jianhui ;
Chang, Christiana ;
Atobe, Satoshi ;
Fukunaga, Hisao ;
Watanabe, Tomonori ;
Liu, YaoLu ;
Ning, HuiMing ;
Li, JinHua ;
Li, Yuan ;
Zhao, Yinghua .
NANOSCALE, 2012, 4 (22) :7250-7255
[7]   Functionalized Graphene Sheet-Poly(vinylidene fluoride) Conductive Nanocomposites [J].
Ansari, Seema ;
Giannelis, Emmanuel P. .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2009, 47 (09) :888-897
[8]   Fabrication of composite PVDF-ZnO nanofiber mats by electrospinning for energy scavenging application with enhanced efficiency [J].
Bafqi, Mohammad Sajad Sorayani ;
Bagherzadeh, Roohollah ;
Latifi, Masoud .
JOURNAL OF POLYMER RESEARCH, 2015, 22 (07)
[9]   Influence of processing conditions on polymorphic behavior, crystallinity, and morphology of electrospun poly(VInylidene fluoride) nanofibers [J].
Baqeri, Maedeh ;
Abolhasani, Mohammad Mahdi ;
Mozdianfard, Mohammad Reza ;
Guo, Qipeng ;
Oroumei, Azam ;
Naebe, Minoo .
JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (30)
[10]   Promising Piezoelectric Properties of New ZnO@Octadecylamine Adduct [J].
Bettini, Simona ;
Pagano, Rosanna ;
Bonfrate, Valentina ;
Maglie, Emanuela ;
Manno, Daniela ;
Serra, Antonio ;
Valli, Ludovico ;
Giancane, Gabriele .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (34) :20143-20149