Solid-state aggregation of mercury bis-acetylides, Hg(CCR)2, R = Ph, SiMe3

被引：41

作者：

Faville, SJ ^{[1
]}

Henderson, W ^{[1
]}

Mathieson, TJ ^{[1
]}

Nicholson, BK ^{[1
]}

机构：

[1] Univ Waikato, Dept Chem, Hamilton, New Zealand

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 02期

关键词：

mercury; acetylides; mercuriophilic interactions; aggregation;

D O I：

10.1016/S0022-328X(98)01196-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of Hg(C=CR)(2) (R = Ph, SiMe3) show unusual aggregation in the solid state. When R = Ph there are eight independent molecules in the asymmetric unit, while for R = SiMe3 there are pentameric aggregates. The Hg ... Hg distances are 3.7-4.0 Angstrom, possibly indicating weak mercuriophilic interactions, but the main driving force for clustering appears to be interactions between Hg atoms and the C=C bonds of adjacent molecules. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：363 / 369

页数：7

共 25 条

[1] On the additivity of van der Waals radii [J].

Batsanov, SS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (10) :1541-1545

[2] SYNTHESIS AND CHARACTERIZATION OF BIS(ETA(2)-ALKYNE)DIHALOGENO-MERCURY(II) COMPOUNDS - CRYSTAL-STRUCTURE OF [NBU(4)](2)-[(CIS-PT(C6F5)(2)(C-CSIME(3))(2))HGBR2]CENTER-DOT-CH2CL2 [J].

BERENGUER, JR ;

FORNIES, J ;

LALINDE, E ;

MARTIN, A ;

MORENO, MT .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (23) :3343-3348

[3] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY [J].

BLESSING, RH .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :33-38

[4] REINVESTIGATION OF ORTHO-PHENYLENE MERCURIALS .2. STRUCTURE OF "TRIBENZO[B,E,H][1,4,7]TRIMERCURONIN [J].

BROWN, DS ;

MASSEY, AG ;

WICKENS, DA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAY) :1695-1697

[5] Convenient synthesis of alkynyl aryl seleno- and telluro-ethers [J].

Cook, DJ ;

Hill, AF ;

Wilson, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (07) :1171-1173

[6] (TERT-BUTYL ISOCYANIDE)CHLOROGOLD(I) [J].

EGGLESTON, DS ;

CHODOSH, DF ;

WEBB, RL ;

DAVIS, LL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 :36-38

[7]

Grohmann A., 1995, COMPREHENSIVE ORGANO, VII

[8] DIBENZYLMERCURY [J].

HITCHCOCK, PB .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (MAR) :746-747

[9] The identification of monosubstituted acetylenes derivatives of diethinyl mercury [J].

Johnson, JR ;

McEwen, WL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1926, 48 (01) :469-476

[10] Trigonal-planar-coordinated organogold(I) complexes stabilized by organometallic 1,4-diynes: Reaction behavior, structure, and bonding [J].

Kohler, K ;

Silverio, SJ ;

HylaKryspin, I ;

Gleiter, R ;

Zsolnai, L ;

Driess, A ;

Huttner, G ;

Lang, H .

ORGANOMETALLICS, 1997, 16 (23) :4970-4979

← 1 2 3 →