Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands

被引：111

作者：

Fürstner, A ^{[1
]}

Krause, H ^{[1
]}

Lehmann, CW ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 22期

关键词：

D O I：

10.1039/b108132b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to the N-heterocyclic carbene (NHC) 1, the homologous N-heterocyclic silylene (NHS) 4 acts as a bridging ligand to Pd(0), giving rise to the dinuclear complex 5 which is catalytically active in Suzuki reactions.

引用

页码：2372 / 2373

页数：2

共 45 条

[1] Ruthenium carbene complexes with imidazolin-2-ylidene ligands allow the formation of tetrasubstituted cycloalkenes by RCM [J].

Ackermann, L ;

Fürstner, A ;

Weskamp, T ;

Kohl, FJ ;

Herrmann, WA .

TETRAHEDRON LETTERS, 1999, 40 (26) :4787-4790

[2]

[Anonymous], COMMENTS INORG CHEM, DOI 10.1080/02603599008048649

[3] Looking for stable carbenes: The difficulty in starting anew [J].

Arduengo, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :913-921

[4] N-heterocyclic carbenes Part 26.: N-heterocyclic carbene complexes of palladium(0):: synthesis and application in the Suzuki cross-coupling reaction [J].

Böhm, VPW ;

Gstöttmayr, CWK ;

Weskamp, T ;

Herrmann, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 595 (02) :186-190

[5] Rhodium carbene complexes: Highly selective catalysts for the hydroformylation of styrene derivatives [J].

Chen, AC ;

Ren, L ;

Decken, A ;

Crudden, CM .

ORGANOMETALLICS, 2000, 19 (18) :3459-3461

[6] Reactions of hydrosilanes with transition-metal complexes: Formation of stable transition-metal silyl compounds [J].

Corey, JY ;

Braddock-Wilking, J .

CHEMICAL REVIEWS, 1999, 99 (01) :175-292

[7] SILYLENE COMPLEXES FROM A STABLE SILYLENE AND METAL-CARBONYLS - SYNTHESIS AND STRUCTURE OF [NI((BU(T)N-CH=CH-NBU(T))SI)(2)(CO)(2)], A DONOR-FREE BIS-SILYLENE COMPLEX [J].

DENK, M ;

HAYASHI, RK ;

WEST, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) :33-34

[8] SYNTHESIS AND STRUCTURE OF A STABLE SILYLENE [J].

DENK, M ;

LENNON, R ;

HAYASHI, R ;

WEST, R ;

BELYAKOV, AV ;

VERNE, HP ;

HAALAND, A ;

WAGNER, M ;

METZLER, N .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (06) :2691-2692

[9] Synthesis of chiral triazolinylidene and imidazolinylidene transition metal complexes and first application in asymmetric catalysis [J].

Enders, D ;

Gielen, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 617 (01) :70-80

[10] EFFICIENT FORMATION AND CLEAVAGE OF DISILANES BY POTASSIUM-GRAPHITE - SILYLATION WITH SILYL METAL REAGENTS [J].

FURSTNER, A ;

WEIDMANN, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (01) :15-21

← 1 2 3 4 5 →