Studies of the construction of coordination polymers using linear pyridyl-donor ligands

被引：156
作者：
Batten, SR [1 ]
Jeffery, JC
Ward, MD
机构：
[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源：
INORGANICA CHIMICA ACTA | 1999年 / 292卷 / 02期
关键词：
crystal structures; copper complexes; silver complexes; coordination polymer complexes;
D O I：
10.1016/S0020-1693(99)00203-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and structural characterisation of [Cu(4,4'-bipyridine)X], X = Br (1), I (2), [Cu(bpe)(2)](BF(4)). MeCN (3), bpe = 1,2-bis(4-pyridyl)ethene, [Ag(bpp)](NO(3)) (4), bpp = 1,3-bis(bpyridyl)propane, and [H(2)bpeb](NO(3))(2) (5), bpeb = 1,4-bis[2-(4-pyridyl)ethenyl]benzene, are reported. Compounds 1 and 2 contain Cu(2)X(2) dimers bridged by 4,4'-bipyridine ligands into (6,3) sheets which display inclined 2D interpenetration. Five interpenetrating diamondoid networks are seen in the structure of 3, while 4 is composed of sinusoidal Ag(bpp) chains and NO(3)(-) counterions. Compound 5 contains protonated bpeb molecules hydrogen bonding to NO(3)(-) counterions. (C) 1999 Elsevier Science S.A. All rights reserved.
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收藏
页码：231 / 237
页数：7
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