Preparation and characterization of manganese dioxides with nano-sized tunnel structures for zinc ion storage

被引:192
作者
Wei, Chunguang [1 ,2 ]
Xu, Chengjun [1 ]
Li, Baohua [1 ]
Du, Hongda [1 ]
Kang, Feiyu [1 ,2 ]
机构
[1] Tsinghua Univ, Adv Mat Inst, Grad Sch Shenzhen, Shenzhen 518055, Guangdong, Peoples R China
[2] Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
Nanostructures; Chemical synthesis; Crystal structure; Microstructure; ELECTROCHEMICAL PROPERTIES; MNO2; MECHANISM; FACILE;
D O I
10.1016/j.jpcs.2011.11.038
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
alpha-, beta-, gamma-, and delta-types manganese dioxide (MnO2) with different tunnel structures and morphologies have been successfully synthesized by a common liquid co-precipitation method based on the redox reactions of Mn4+ and Mn2+. The crystalline tunnel structure, particle size, and morphology of the manganese dioxides have been characterized by X-ray diffraction and scanning electron microscopy. It is found that the morphology of as-prepared MnO2 changes with the concentration of raw materials. Depending on the procedure of preparation, spherical particles about 20 nm in diameter, nanorods of 40-100 nm in length and about 20 nm in diameter, or interlocked nanosheet of 10-20 nm in thickness are formed. The effect of crystallographic forms of MnO2 on Zn2+ ion storage properties has been revealed. The electrochemical performances of the alpha-, beta-, gamma-, and delta-MnO2 were characterized by the galvanostatic charge-discharge and cyclic voltammetry tests. The delta-MnO2 shows the highest specific capacity (269 mAh g(-1)) in the new zinc battery system Zn[ZnSO4(aq)]MnO2. Crown Copyright (C) 2012 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:1487 / 1491
页数:5
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