Crystal structure of bis{4-[(4-methvlbenzyl)oxy]-N′-(4-methylbenzyhdene)benzohydraziaatoinickel(II)

被引:4
作者
Al Banna, Md Hasan [1 ]
Howlader, Md Belayet Hossain [1 ]
Miyatake, Ryuta [2 ]
Sheikh, Md Chanmiya [3 ]
Zangrando, Ennio [4 ]
机构
[1] Rajshahi Univ, Dept Chem, Rajshahi 6205, Bangladesh
[2] Univ Toyama, Ctr Environm Conservat & Res Safety, 3190 Gofuku, Toyama 9308555, Japan
[3] Okayama Univ Sci, Fac Sci, Dept Appl Sci, Okayama, Japan
[4] Univ Trieste, Dept Chem & Pharmaceut SCi, Trieste, Italy
关键词
crystal structure; nickel(II) complex; square-planar coordination; aroylhydrazone ligand; X-RAY; HYDRAZONE LIGANDS; BOND LENGTHS; COMPLEXES; COORDINATION;
D O I
10.1107/S2056989022009392
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Ni(C23H21N2O2)(2)], the central Ni-II atom is located on an inversion centre and exhibits a slightly distorted square-planar N2O2 coordination environment. A trans-configuration of the N,O chelating ligands results from the imposed site symmetry of the central Ni-II atom. In the crystal, individual molecules stack along the a axis through weak pi-pi stacking interactions between the phenyl rings.
引用
收藏
页码:1081 / +
页数:9
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