Double-Armed Benzo-15-crown-5 Ligands and Complexes and Single Crystal Structure Determination

被引：6

作者：

Sahin, Duygu ^{[1
]}

Suzen, Yasemin ^{[2
]}

Hayvali, Zeliha ^{[1
]}

机构：

[1] Ankara Univ, Dept Chem, Fac Sci, TR-06100 Ankara, Turkey

[2] Anadolu Univ, Fac Sci, Dept Chem, TR-26470 Eskisehir, Turkey

来源：

HETEROATOM CHEMISTRY | 2014年 / 25卷 / 01期

关键词：

TRANSITION-METAL-COMPLEXES; CROWN-ETHERS; SCHIFF-BASE; SPECTROSCOPIC CHARACTERIZATION; MOLECULAR DESIGN; DERIVATIVES; BEHAVIOR; SODIUM;

D O I：

10.1002/hc.21134

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work describes the syntheses and characterizations of double-armed benzo-15-crown-5 containing nitro (1), amine (2), and imine (3-5) groups, and their sodium complexes (1a-5a). Structures of the ligands (1-5) and sodium complexes (1a-5a) were identified via elemental analyses, and infrared, H-1- nuclear magnetic resonance (NMR), C-13-NMR, and mass spectrometry. The metal extractions were examined by using ultravoilet-visible spectrophotometry. Single crystal for 2 was successfully obtained, and its X-ray crystal structure was resolved. The compound 2 crystallizes in triclinic, space group p-1 with a = 9.1420(3), b = 14.9580(4), c = 20.4110(5), and Z = 4. (C) 2013 Wiley Periodicals, Inc.

引用

页码：43 / 54

页数：12

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