A straightforward route to obtain zirconium based metal-organic gels

被引:53
作者
Santos-Lorenzo, Janire [1 ]
San Jose-Velado, Ruben [1 ]
Albo, Jonathan [2 ]
Beobide, Garikoitz [1 ]
Castano, Pedro [3 ]
Castillo, Oscar [1 ]
Luque, Antonio [1 ]
Perez-Yanez, Sonia [1 ,4 ]
机构
[1] Univ Basque Country, Fac Ciencia & Tecnol, Dept Quim Inorgan, Apartado 644, E-48080 Bilbao, Spain
[2] Univ Cantabria, Dept Ingn Quim & Biomol, E-39005 Santander, Spain
[3] Univ Basque Country, Fac Ciencia & Tecnol, Dept Ingn Quim, Apartado 644, E-48080 Bilbao, Spain
[4] Univ Basque Country, Fac Farm, Dept Quim Inorgan, E-01006 Vitoria, Spain
关键词
Zirconium; Metal-organic gel; CO2; electroreduction; Porosity; Green chemistry; FRAMEWORK MATERIALS; EFFICIENT; ACIDITY; DESIGN; GREEN;
D O I
10.1016/j.micromeso.2019.04.008
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Zirconium based metal-organic gels are obtained through a rapid method at room temperature, employing green solvents, in which the role of water is important. These porous materials, decorated with Bronsted acid sites, show outstanding thermal and chemical stability prompting them as stable catalyst in the continuous electroreduction of CO2.
引用
收藏
页码:128 / 132
页数:5
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