A straightforward route to obtain zirconium based metal-organic gels

被引：53

作者：

Santos-Lorenzo, Janire ^{[1
]}

San Jose-Velado, Ruben ^{[1
]}

Albo, Jonathan ^{[2
]}

Beobide, Garikoitz ^{[1
]}

Castano, Pedro ^{[3
]}

Castillo, Oscar ^{[1
]}

Luque, Antonio ^{[1
]}

Perez-Yanez, Sonia ^{[1
,4
]}

机构：

[1] Univ Basque Country, Fac Ciencia & Tecnol, Dept Quim Inorgan, Apartado 644, E-48080 Bilbao, Spain

[2] Univ Cantabria, Dept Ingn Quim & Biomol, E-39005 Santander, Spain

[3] Univ Basque Country, Fac Ciencia & Tecnol, Dept Ingn Quim, Apartado 644, E-48080 Bilbao, Spain

[4] Univ Basque Country, Fac Farm, Dept Quim Inorgan, E-01006 Vitoria, Spain

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2019年 / 284卷

关键词：

Zirconium; Metal-organic gel; CO2; electroreduction; Porosity; Green chemistry; FRAMEWORK MATERIALS; EFFICIENT; ACIDITY; DESIGN; GREEN;

D O I：

10.1016/j.micromeso.2019.04.008

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Zirconium based metal-organic gels are obtained through a rapid method at room temperature, employing green solvents, in which the role of water is important. These porous materials, decorated with Bronsted acid sites, show outstanding thermal and chemical stability prompting them as stable catalyst in the continuous electroreduction of CO2.

引用

页码：128 / 132

页数：5

共 35 条

[1] Towards the electrochemical conversion of carbon dioxide into methanol [J].

Albo, J. ;

Alvarez-Guerra, M. ;

Castano, P. ;

Irabien, A. .

GREEN CHEMISTRY, 2015, 17 (04) :2304-2324

[2] Copper-Based Metal-Organic Porous Materials for CO2 Electrocatalytic Reduction to Alcohols [J].

Albo, Jonathan ;

Vallejo, Daniel ;

Beobide, Garikoitz ;

Castillo, Oscar ;

Castano, Pedro ;

Irabien, Angel .

CHEMSUSCHEM, 2017, 10 (06) :1100-1109

[3] Zr-based metal-organic frameworks: design, synthesis, structure, and applications [J].

Bai, Yan ;

Dou, Yibo ;

Xie, Lin-Hua ;

Rutledge, William ;

Li, Jian-Rong ;

Zhou, Hong-Cai .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (08) :2327-2367

[4] Towards industrial use of metal-organic framework: Impact of shaping on the MOF properties [J].

Bazer-Bachi, D. ;

Assie, L. ;

Lecocq, V. ;

Harbuzaru, B. ;

Falk, V. .

POWDER TECHNOLOGY, 2014, 255 :52-59

[5] Gel-based morphological design of zirconium metal-organic frameworks [J].

Bueken, Bart ;

Van Velthoven, Niels ;

Willhammar, Tom ;

Stassin, Timothee ;

Stassen, Ivo ;

Keen, David A. ;

Baron, Gino V. ;

Denayer, Joeri F. M. ;

Ameloot, Rob ;

Bals, Sara ;

De Vos, Dirk ;

Bennett, Thomas D. .

CHEMICAL SCIENCE, 2017, 8 (05) :3939-3948

[6] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[7] Shaping of Metal-Organic Frameworks: From Fluid to Shaped Bodies and Robust Foams [J].

Chen, Yifa ;

Huang, Xianqiang ;

Zhang, Shenghan ;

Li, Siqing ;

Cao, Sijia ;

Pei, Xiaokun ;

Zhou, Junwen ;

Feng, Xiao ;

Wang, Bo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (34) :10810-10813

[8] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[9] Stability and degradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit [J].

DeCoste, Jared B. ;

Peterson, Gregory W. ;

Jasuja, Himanshu ;

Glover, T. Grant ;

Huang, You-gui ;

Walton, Krista S. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5642-5650

[10] Electrochemistry of metal-organic frameworks:: A description from the voltammetry of microparticles approach [J].

Domenech, Antonio ;

Garcia, Hermenegildo ;

Domenech-Carbo, Maria Teresa ;

Xamena, F. X. L. I. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (37) :13701-13711

← 1 2 3 4 →