Selective monoacylation of ferrocene - An eco-friendly procedure on the solid phase of alumina

被引:22
作者
Ranu, BC [1 ]
Jana, U [1 ]
Majee, A [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Organ Chem, Calcutta 700032, W Bengal, India
关键词
D O I
10.1039/a808890j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple, efficient and environment-friendly procedure has been developed for acylation of ferrocene with direct use of carboxylic acid in the presence of trifluoroacetic anhydride on the solid phase of alumina. A wide range of structurally varied carboxylic acids have been found to provide selectively the monoacylated products in high yields.
引用
收藏
页码:33 / 34
页数:2
相关论文
共 12 条
[1]  
Bhattacharyya S, 1998, SYNLETT, P837
[2]  
BUBLITZ DE, 1969, ORG REACTIONS, V17, P23
[3]  
Fukuzawa S, 1998, SYNLETT, P727
[4]   METALLOMESOGENS - METAL-COMPLEXES IN ORGANIZED FLUID PHASES [J].
GIROUDGODQUIN, AM ;
MAITLIS, PM .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :375-402
[5]   Asymmetric dihydroxylation reactions leading to novel chiral ferrocene derivatives [J].
Jary, WG ;
Baumgartner, J .
TETRAHEDRON-ASYMMETRY, 1998, 9 (12) :2081-2085
[6]   Towards new ferrocenyl ligands for asymmetric catalysis [J].
Kagan, HB ;
Diter, P ;
Gref, A ;
Guillaneux, D ;
Szymczak, AM ;
Rebiere, F ;
Riant, O ;
Samuel, O ;
Taudien, S .
PURE AND APPLIED CHEMISTRY, 1996, 68 (01) :29-36
[7]  
PLESSKE K, 1962, ANGEW CHEM INT EDIT, V1, P312
[8]   Simple and improved procedure for regioselective acylation of aromatic ethers with carboxylic acids on the solid surface of alumina in the presence of trifluoroacetic anhydride [J].
Ranu, BC ;
Ghosh, K ;
Jana, U .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (26) :9546-9547
[9]   IMPROVING ENZYME-ELECTRODE CONTACTS BY REDOX MODIFICATION OF COFACTORS [J].
RIKLIN, A ;
KATZ, E ;
WILLNER, I ;
STOCKER, A ;
BUCKMANN, AF .
NATURE, 1995, 376 (6542) :672-675
[10]   A NEW APPROACH TO CHIRAL CYCLOPENTADIENYLMETAL COMPLEXES [J].
SCHWINK, L ;
VETTEL, S ;
KNOCHEL, P .
ORGANOMETALLICS, 1995, 14 (11) :5000-5001