Synthesis, Characterization, Thermal Stability and Decomposition Mechanism of [Ru(C12H8N2)3](C4H2O4)(C4H3O4)(C4H4O4)•4H2O

被引：0

作者：

Shui, Miao ^{[1
]}

Shu, Jie ^{[1
]}

Li, Rongsheng ^{[1
]}

Song, Yue ^{[1
]}

Ren, Yuanlong ^{[1
]}

Wang, Qingchun ^{[1
]}

机构：

[1] Fac Chem Engn & Mat Sci, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2012年 / 24卷 / 11期

基金：

浙江省自然科学基金;

关键词：

Masterplot; Ru(III) complex; Crystal structure; Thermal analysis; THERMOGRAVIMETRIC DATA; KINETIC-ANALYSIS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of Ru(III) complex [Ru(C12H8N2)(3)](C4H2O4)(C4H3O4)(C4H4O4)center dot 4H(2)O is synthesized and characterized. Single-crystal X-ray diffraction shows that the complex belongs to triclinic system, space group P-1, M-r = 1058.94 and the cell parameters are a = 12.057(2) angstrom, b = 12.450(3) angstrom, c = 17.110(3) angstrom, alpha = 76.95(3)degrees, beta = 89.87(3)degrees, gamma = 63.82(3)degrees, V = 2231.5(8) angstrom(3), Z = 2, D-c = 1.576 g/cm(3), F(000) = 1086. The thermal stability and decomposition behaviour of the complex is intensively investigated by the method of masterplot, Coats and Redfern and Achar, Brindley and Sharp.

引用

页码：4858 / 4862

页数：5

共 15 条

[1] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].