The reactions of singlet oxygen with β-chlorosulfides.: The role of hydroperoxy sulfonium ylides in the oxidative destruction of chemical warfare simulants

被引：19

作者：

Toutchkine, A ^{[1
]}

Clennan, EL ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 36期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(99)01304-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactions of singlet oxygen with 2-chloroethyl ethyl sulfide and 3-chlorothiane are reported. In both cases elimination of NCI to produce oc,B-unsaturated sulfoxides is observed. The experimental results implicate a hydroperoxy sulfonium ylide as a transition state or intermediate in an E2 or E1cb elimination, respectively. (C) 1999 Elsevier Science Ltd. Ail rights reserved.

引用

页码：6519 / 6522

页数：4

共 5 条

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Jensen, F
Greer, A
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) : 4439 - 4449
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