Ruthenium(II) Complexes of an Imidazole Carboxamido Ligand for Base-Free Transfer Hydrogenation in Air

被引：1

作者：

Citta, Richard J. ^{[1
]}

Koteles, Brandon L. ^{[1
]}

Delgado-Perez, Brenda ^{[1
]}

Chan, Benny C. ^{[2
]}

Kalman, Steven E. ^{[1
]}

机构：

[1] Stockton Univ, Sch Nat Sci & Math, Chem Program, Galloway, NJ 08205 USA

[2] Coll New Jersey, Chem Dept, Ewing, NJ 08618 USA

来源：

ORGANOMETALLICS | 2022年 / 41卷 / 21期

基金：

美国国家科学基金会;

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; CATALYTIC TRANSFER HYDROGENATION; CARBONYL-COMPOUNDS; IRIDIUM; KETONES; REACTIVITY; CHEMISTRY; MECHANISM; BONDS;

D O I：

10.1021/acs.organomet.2c00433

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two half-sandwich ruthenium(II) complexes of an imidazole-2-carboxamido ligand have been synthesized and characterized by nuclear magnetic resonance spectroscopy, elemental analysis, and, in one case, single-crystal X-ray diffraction. Both complexes serve as precatalysts for base-free transfer hydrogenation under aerobic conditions. A substrate scope study with a range of ketones and aldehydes was performed, and a preliminary investigation into the mechanism of catalysis was undertaken. These complexes represent relatively rare examples of transfer hydrogenation catalysts that do not require an inert atmosphere and an exogenous base.

引用

页码：3004 / 3013

页数：10

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