Highly porous metal-organic framework sustained with 12-connected nanoscopic octahedra

被引：60
作者：
Lu, Weigang [1 ]
Yuan, Daqiang [2 ]
Makal, Trevor A. [1 ]
Wei, Zhangwen [1 ]
Li, Jian-Rong [1 ]
Zhou, Hong-Cai [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 05期
基金：
美国国家科学基金会;
关键词：
HYDROGEN STORAGE; SURFACE-AREAS; POROSITY; CONSTRUCTION; LIGANDS; ROUTE;
D O I：
10.1039/c2dt32479b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two dicopper(II)-paddlewheel-based metal-organic frameworks (PCN-81 and -82) have been synthesized by using tetratopic ligands featuring 90 degrees-carbazole-dicarboxylate moieties. Both adopt 12-connected tfb topology with nanoscopic octahedra as building units. The freeze-dried PCN-82 shows Brunauer-Emmett-Teller (BET) and Langmuir surface areas as high as 4488 and 4859 m(2) g(-1), respectively. It also exhibits high H-2-adsorption capacity at low pressure (300 cm(3) g(-1) or 2.6 wt% at 77 K and 1 bar), which can be attributed to its high surface area, microporosity, and open metal sites.
引用
收藏
页码：1708 / 1714
页数：7
相关论文
共 46 条
[1]   Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework [J].
An, Jihyun ;
Farha, Omar K. ;
Hupp, Joseph T. ;
Pohl, Ehmke ;
Yeh, Joanne I. ;
Rosi, Nathaniel L. .
NATURE COMMUNICATIONS, 2012, 3
[2]   A route to high surface area, porosity and inclusion of large molecules in crystals [J].
Chae, HK ;
Siberio-Pérez, DY ;
Kim, J ;
Go, Y ;
Eddaoudi, M ;
Matzger, AJ ;
O'Keeffe, M ;
Yaghi, OM .
NATURE, 2004, 427 (6974) :523-527
[3]   Hydrogen storage in metal-organic frameworks [J].
Collins, David J. ;
Zhou, Hong-Cai .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3154-3160
[4]  
DINCA M, 2007, ANGEW CHEM, V119, P1441
[5]   Designing Higher Surface Area Metal-Organic Frameworks: Are Triple Bonds Better Than Phenyls? [J].
Farha, Omar K. ;
Wilmer, Christopher E. ;
Eryazici, Ibrahim ;
Hauser, Brad G. ;
Parilla, Philip A. ;
O'Neill, Kevin ;
Sarjeant, Amy A. ;
Nguyen, SonBinh T. ;
Snurr, Randall Q. ;
Hupp, Joseph T. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (24) :9860-9863
[6]  
Farha OK, 2010, NAT CHEM, V2, P944, DOI [10.1038/NCHEM.834, 10.1038/nchem.834]
[7]   A chromium terephthalate-based solid with unusually large pore volumes and surface area [J].
Férey, G ;
Mellot-Draznieks, C ;
Serre, C ;
Millange, F ;
Dutour, J ;
Surblé, S ;
Margiolaki, I .
SCIENCE, 2005, 309 (5743) :2040-2042
[8]   Hybrid porous solids:: past, present, future [J].
Ferey, Gerard .
CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214
[9]   Ultrahigh Porosity in Metal-Organic Frameworks [J].
Furukawa, Hiroyasu ;
Ko, Nakeun ;
Go, Yong Bok ;
Aratani, Naoki ;
Choi, Sang Beom ;
Choi, Eunwoo ;
Yazaydin, A. Oezguer ;
Snurr, Randall Q. ;
O'Keeffe, Michael ;
Kim, Jaheon ;
Yaghi, Omar M. .
SCIENCE, 2010, 329 (5990) :424-428
[10]   High H2 storage of hexagonal metal-organic frameworks from first-principles-based grand canonical Monte Carlo simulations [J].
Han, Sang Soo ;
Goddard, William A., III .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (35) :13431-13436
12345