Reactions of arylglyoxals with tetrasulfur tetranitrides (S4N4):: Formation of 2-aroyl-5-arylimidazoles and 2-aroyl-5-aryloxazoles

被引：7
|
作者：
Kong, YC [1 ]
Kim, K [1 ]
机构：
[1] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 1999年 / 36卷 / 04期
关键词：
D O I：
10.1002/jhet.5570360414
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of arylglyoxal monohydrates with tetrasulfur tetranitride in p-dioxane at reflux afforded 2-aroyl-5-arylimidizoles and 2-aroyl-5-aryloxazoles in 10 to 31% and 17 to 32% yields, respectively. With non-hydrate of arylglyoxals, yields of the latter increase somewhat, whereas essentially no changes in yields of the former were observed. A mechanism is proposed for the formation of the products.
引用
收藏
页码：911 / 915
页数：5
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