Effect of Chloride on Semiconducting Properties of Passive Films Formed on Supermartensitic Stainless Steel in NaHCO3 Solution

被引：25

作者：

Han Xiao-chen ^{[1
]}

Li Jun ^{[1
]}

Zhao Kun-yu ^{[1
]}

Zhang Wei ^{[2
]}

Su Jie ^{[3
]}

机构：

[1] Kunming Univ Sci & Technol, Coll Mat Sci & Engn, Kunming 650093, Yunnan, Peoples R China

[2] CISRI Qingdao Marine Corros Inst, Qingdao 266071, Shandong, Peoples R China

[3] Cent Iron & Steel Res Inst, Inst Struct Mat, Beijing 100081, Peoples R China

来源：

JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL | 2013年 / 20卷 / 05期

关键词：

supermartensitic stainless steel; passive film; capacitance measurement; semiconducting property; chloride ion; BORATE BUFFER; 304-STAINLESS-STEEL; POTENTIALS; BREAKDOWN; IRON; XPS; FE;

D O I：

10.1016/S1006-706X(13)60101-6

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The effects of chloride ion on the electrochemical behavior and the semiconducting properties of the passive film on supermartensitic stainless steel in 0.5 mol/L NaHCO3 solution were investigated using potentiodynamic polarization, the potentiostatic current transients and Mott-Schottky analysis. The results indicated that chloride ion narrowed passivation region and improved pitting susceptibility. The steady state current densities were independent of film-formed potentials, which was in good agreement with the assumption of the point defect model (PDM). The capacitance results showed the fact that the passive films had a multilayer character. The defect density decreased with increasing passive film formation potential. The chloride ion induced changes of the acceptor densities and donor densities of the passive films.

引用

页码：74 / 79

页数：6

共 25 条

[1] MOTT-SCHOTTKY PLOT OF THE PASSIVE FILM FORMED ON IRON IN NEUTRAL BORATE AND PHOSPHATE SOLUTIONS [J].

AZUMI, K ;

OHTSUKA, T ;

SATO, N .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (06) :1352-1357

[2] Capacitance behaviour of passive films on ferritic and austenitic stainless steel [J].

Carmezim, MJ ;

Simoes, AM ;

Montemor, MF ;

Belo, MD .

CORROSION SCIENCE, 2005, 47 (03) :581-591

[3] Photoelectrochemical analysis on the passive film formed on Fe-20Cr in pH 8.5 buffer solution [J].

Cho, EA ;

Kwon, H ;

Macdonald, DD .

ELECTROCHIMICA ACTA, 2002, 47 (10) :1661-1668

[4] INTERPRETATION OF MOTT-SCHOTTKY PLOTS DETERMINED AT SEMICONDUCTOR-ELECTROLYTE SYSTEMS [J].

DEGRYSE, R ;

GOMES, WP ;

CARDON, F ;

VENNIK, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (05) :711-712

[5] The iron passive film breakdown in chloride media may be mediated by transient chloride-induced surface states located within the band gap [J].

Díez-Pérez, I ;

Vericat, C ;

Gorostiza, P ;

Sanz, F .

ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (04) :627-632

[6] Electrooxidation of stainless steel AISI 304 in carbonate aqueous solution at pH8 [J].

Drogowska, M ;

Menard, H ;

Brossard, L .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1996, 26 (02) :217-225

[7] The semiconducting properties of passive films formed on AISI 316 L and AISI 321 stainless steels: A test of the point defect model (PDM) [J].

Fattah-alhosseini, A. ;

Soltani, F. ;

Shirsalimi, F. ;

Ezadi, B. ;

Attarzadeh, N. .

CORROSION SCIENCE, 2011, 53 (10) :3186-3192

[8] Electrochemical and analytical investigation of passive films formed on stainless steels in alkaline media [J].

Freire, L. ;

Catarino, M. A. ;

Godinho, M. I. ;

Ferreira, M. J. ;

Ferreira, M. G. S. ;

Simoes, A. M. P. ;

Montemor, M. F. .

CEMENT & CONCRETE COMPOSITES, 2012, 34 (09) :1075-1081

[9] Impedance spectroscopy at semiconductor electrodes: Review and recent developments [J].

Gomes, WP ;

Vanmaekelbergh, D .

ELECTROCHIMICA ACTA, 1996, 41 (7-8) :967-973

[10] THE ELECTRONIC-STRUCTURE OF PASSIVE FILMS FORMED ON STAINLESS-STEELS [J].

HAKIKI, NE ;

BOUDIN, S ;

RONDOT, B ;

BELO, MD .

CORROSION SCIENCE, 1995, 37 (11) :1809-1822

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