Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties

被引：34
作者：
Adelani, Pius O.
Oliver, Allen G.
Albrecht-Schmitt, Thomas E. [1 ]
机构：
[1] Univ Notre Dame, Dept Civil Engn & Geol Sci, Notre Dame, IN 46556 USA
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 09期
关键词：
BOND-VALENCE PARAMETERS; COORDINATION POLYMERS; URANIUM; CLUSTERS; OXIDE; CHEMISTRY;
D O I：
10.1021/ic300035n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel uranium heteropolyoxometalate, [H3O]4[Ni(H2O)(3)](4) {Ni[(UO2)(PO3C6H4CO2)](3)-(PO4H)}(4)center dot 2.72H(2)O, has been prepared under mild hydrothermal conditions using the diethyl(2-ethoxycarbonylphenyl)phosphonate ligand and in situ ligand synthesis of the HPO42- anion. The cluster is derived from a common UO7, pentagonal bipyrarnid and is constructed by employing nickel(II) metal ions as linkers. The 3d-5f heteropolyoxometalate core incorporates 12 classical pentagonal uranyl groups and four Ni2+ octahedral units.
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收藏
页码：4885 / 4887
页数：3
相关论文
共 36 条
[1]   Heterobimetallic Copper(II) Uranyl Carboxyphenylphosphonates [J].
Adelani, Pius O. ;
Albrecht-Schmitt, Thomas E. .
CRYSTAL GROWTH & DESIGN, 2011, 11 (10) :4676-4683
[2]   Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates [J].
Adelani, Pius O. ;
Oliver, Allen G. ;
Albrecht-Schmitt, Thomas E. .
CRYSTAL GROWTH & DESIGN, 2011, 11 (07) :3072-3080
[3]   Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates [J].
Adelani, Pius O. ;
Albrecht-Schmitt, Thomas E. .
INORGANIC CHEMISTRY, 2010, 49 (12) :5701-5705
[4]   Use of bifunctional phosphonates for the preparation of heterobimetallic 5f-3d systems [J].
Alsobrook, Andrea N. ;
Zhan, Wei ;
Albrecht-Schmitt, Thomas E. .
INORGANIC CHEMISTRY, 2008, 47 (12) :5177-5183
[5]   Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals [J].
Benelli, C ;
Gatteschi, D .
CHEMICAL REVIEWS, 2002, 102 (06) :2369-2387
[6]   Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(IV) cluster:: Synthesis and crystal structure of the first f-element oxide with a M6(μ3-O)8 core [J].
Berthet, JC ;
Thuéry, P ;
Ephritikhine, M .
CHEMICAL COMMUNICATIONS, 2005, (27) :3415-3417
[7]   Formation of Uranium(IV) Oxide Clusters from Uranocene [U(η8-C8H8)2] and Uranyl [UO2X2] Compounds [J].
Berthet, Jean-Claude ;
Thuery, Pierre ;
Ephritikhine, Michel .
INORGANIC CHEMISTRY, 2010, 49 (17) :8173-8177
[8]   Base-Driven Assembly of Large Uranium Oxo/Hydroxo Clusters [J].
Biswas, Biplab ;
Mougel, Victor ;
Pecaut, Jacques ;
Mazzanti, Marinella .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (25) :5744-5747
[9]   BOND-VALENCE PARAMETERS FOR SOLIDS [J].
BRESE, NE ;
OKEEFFE, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197
[10]   Nanoscale uranium-based cage clusters inspired by uranium mineralogy [J].
Burns, P. C. .
MINERALOGICAL MAGAZINE, 2011, 75 (01) :1-25
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