A chain of fused R22(10) and R46(12) rings in the hydrogen-bonded structure of 1,4,8,11-tetraazacyclotetradecane-2,2′-biphenol (1/2)

被引:8
作者
Ferguson, G [1 ]
Gregson, RM
Glidewell, C
机构
[1] Univ Guelph, Dept Chem & Biochem, Guelph, ON N1G 2W1, Canada
[2] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
D O I
10.1107/S0108270199001833
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound is a salt, i.e. 4,11-diaza-1,8-diazoniacyclotetradecane bis[2(2-hydroxyphenyl)phenolate], C10H26N42+.2HOC(6)H(4)C(6)H(4)O(-). The centrosymmetric cation contains two intramolecular N-H...N hydrogen bonds, with an N...N distance of 2.865 (2) Angstrom, and the anion contains an intramolecular O-H...O hydrogen bond, with an O...O distance of 2.486 (2) Angstrom. The ions are linked into continuous chains by means of two types of N-H...O hydrogen bond having N...O distances of 2.682(2) and 3.273 (2) Angstrom.
引用
收藏
页码:815 / 817
页数:3
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