H2S-tolerant oxygen-permeable ceramic membranes for hydrogen separation with a performance comparable to those of palladium-based membranes

被引：64
作者：
Li, Wenping [1 ,2 ]
Cao, Zhongwei [1 ]
Cai, Lili [1 ,2 ]
Zhang, Lixiao [1 ,2 ]
Zhu, Xuefeng [1 ]
Yang, Weishen [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2017年 / 10卷 / 01期
基金：
中国国家自然科学基金;
关键词：
COMPOSITE MEMBRANES; ASYMMETRIC MEMBRANES; PERMEATION BEHAVIOR; STABILITY; PD; ENERGY; NI; TEMPERATURES; ATMOSPHERE; CONDUCTOR;
D O I：
10.1039/c6ee02967a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new method for hydrogen separation to acquire high-purity hydrogen using an oxygen-permeable ceramic membrane is proposed and verified in this work. A high hydrogen separation rate of up to 16.3 mL cm(-2) min(-1) was achieved on an asymmetric dual-phase membrane at 900 degrees C. No performance degradation was observed in a long-term operation with the feed gas containing 200 ppm H2S.
引用
收藏
页码：101 / 106
页数：6
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