H2S-tolerant oxygen-permeable ceramic membranes for hydrogen separation with a performance comparable to those of palladium-based membranes

被引：64

作者：

Li, Wenping ^{[1
,2
]}

Cao, Zhongwei ^{[1
]}

Cai, Lili ^{[1
,2
]}

Zhang, Lixiao ^{[1
,2
]}

Zhu, Xuefeng ^{[1
]}

Yang, Weishen ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2017年 / 10卷 / 01期

基金：

中国国家自然科学基金;

关键词：

COMPOSITE MEMBRANES; ASYMMETRIC MEMBRANES; PERMEATION BEHAVIOR; STABILITY; PD; ENERGY; NI; TEMPERATURES; ATMOSPHERE; CONDUCTOR;

D O I：

10.1039/c6ee02967a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new method for hydrogen separation to acquire high-purity hydrogen using an oxygen-permeable ceramic membrane is proposed and verified in this work. A high hydrogen separation rate of up to 16.3 mL cm(-2) min(-1) was achieved on an asymmetric dual-phase membrane at 900 degrees C. No performance degradation was observed in a long-term operation with the feed gas containing 200 ppm H2S.

引用

页码：101 / 106

页数：6

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