Azafullerene (C59N)2 thin-film field-effect transistors

被引:15
作者
Kumashiro, R [1 ]
Tanigaki, K
Ohashi, H
Tagmatarchis, N
Kato, H
Shinohara, H
Akasaka, T
Kato, K
Aoyagi, S
Kimura, S
Takata, M
机构
[1] Japan Sci & Technol Corp, CREST, Kawaguchi, Japan
[2] Osaka City Univ, Grad Sch Sci, Osaka 558, Japan
[3] Univ Trieste, Trieste, Italy
[4] Nagoya Univ, Dept Chem, Nagoya, Aichi, Japan
[5] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 305, Japan
[6] SPring 8, JASRI, Sayo, Hyogo, Japan
关键词
D O I
10.1063/1.1667013
中图分类号
O59 [应用物理学];
学科分类号
摘要
Thin-film field-effect transistors (FETs) of azafullerene (C59N)(2) are fabricated, and their properties are investigated. The (C59N)(2) FET exhibits n-channel characteristics with the field-effect electron mobility of 3.8x10(-4) cm(2) V-1 s(-1) and the on-off current ratio of 10(3) at room temperature. The observed differences are ascribed to the much smaller grain size and the worse crystallinity of (C59N)(2) thin films, on a basis of low angle x-ray diffraction structural data. The anticipated dimer to monomer conversion with electron carrier injection is not observed. The FET characteristics are discussed from the temperature evolution of the mobilities between (C59N)(2) and C-60 FETs. (C) 2004 American Institute of Physics.
引用
收藏
页码:2154 / 2156
页数:3
相关论文
共 20 条
[1]   Unconventional bonding of azafullerenes: Theory and experiment [J].
Andreoni, W ;
Curioni, A ;
Holczer, K ;
Prassides, K ;
KeshavarzK, M ;
Hummelen, JC ;
Wudl, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (45) :11335-11336
[2]   Organic field-effect transistors with high mobility based on copper phthalocyanine [J].
Bao, Z ;
Lovinger, AJ ;
Dodabalapur, A .
APPLIED PHYSICS LETTERS, 1996, 69 (20) :3066-3068
[3]   FULLERENES WITH METALS INSIDE [J].
CHAI, Y ;
GUO, T ;
JIN, CM ;
HAUFLER, RE ;
CHIBANTE, LPF ;
FURE, J ;
WANG, LH ;
ALFORD, JM ;
SMALLEY, RE .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (20) :7564-7568
[4]   Molecular beam deposited thin films of pentacene for organic field effect transistor applications [J].
Dimitrakopoulos, CD ;
Brown, AR ;
Pomp, A .
JOURNAL OF APPLIED PHYSICS, 1996, 80 (04) :2501-2508
[5]   ORGANIC TRANSISTORS - 2-DIMENSIONAL TRANSPORT AND IMPROVED ELECTRICAL CHARACTERISTICS [J].
DODABALAPUR, A ;
TORSI, L ;
KATZ, HE .
SCIENCE, 1995, 268 (5208) :270-271
[6]   DOPING BUCKY - FORMATION AND PROPERTIES OF BORON-DOPED BUCKMINSTERFULLERENE [J].
GUO, T ;
JIN, CM ;
SMALLEY, RE .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :4948-4950
[7]   C-60 THIN-FILM TRANSISTORS [J].
HADDON, RC ;
PEREL, AS ;
MORRIS, RC ;
PALSTRA, TTM ;
HEBARD, AF ;
FLEMING, RM .
APPLIED PHYSICS LETTERS, 1995, 67 (01) :121-123
[8]   C-70 thin film transistors [J].
Haddon, RC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (12) :3041-3042
[9]   Passivation effects of alumina insulating layer on C60 thin-film field-effect transistors [J].
Horiuchi, K ;
Nakada, K ;
Uchino, S ;
Hashii, S ;
Hashimoto, A ;
Aoki, N ;
Ochiai, Y ;
Shimizu, M .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1911-1912
[10]   ISOLATION OF THE HETEROFULLERENE C59N AS ITS DIMER (C59N)(2) [J].
HUMMELEN, JC ;
KNIGHT, B ;
PAVLOVICH, J ;
GONZALEZ, R ;
WUDL, F .
SCIENCE, 1995, 269 (5230) :1554-1556