A subtle end-group effect on macroscopic physical gelation of triblock copolymer aqueous solutions

被引：266

作者：

Yu, L ^{[1
]}

Zhang, H ^{[1
]}

Ding, JD ^{[1
]}

机构：

[1] Fudan Univ, Key Lab Mol Engn Polymers, Dept Macromol Sci, Shanghai 200433, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 14期

关键词：

block copolymers; gels; phase transitions; self-assembly; sol-gel processes;

D O I：

10.1002/anie.200503575

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) In the end: Alkyl end groups can induce a thermoreversible sol-gel transition in an otherwise sol-like suspension by affecting the macroscopic self-assembly behavior. The picture shows PLGA-PEG-PLGA triblock copolymer/water mixtures in the sol (polymer a), gel (polymers b and c), and precipitation states (polymer d). PLGA = poly(lactic acid-co-glycolic acid), PEG = poly(ethylene glycol). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2232 / 2235

页数：4

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