Catalytic nanomotors: fabrication, mechanism, and applications

被引:63
作者
Gibbs, John [1 ]
Zhao, Yiping [1 ]
机构
[1] Univ Georgia, Dept Phys & Astron, Nanoscale Sci & Engn Ctr, Athens, GA 30602 USA
基金
美国国家科学基金会;
关键词
nanomotors; catalysis; glancing angle deposition (GLAD); bubble propulsion; self-electrophoresis;
D O I
10.1007/s11706-011-0120-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Catalytic nanomotors are nano-to-micrometer-sized actuators that carry an on-board catalyst and convert local chemical fuel in solution into mechanical work. The location of this catalyst as well as the geometry of the structure dictate the swimming behaviors exhibited. The nanomotors can occur naturally in organic molecules, combine natural and artificial parts to form hybrid nanomotors or be purely artificial. Fabrication techniques consist of template directed electroplating, lithography, physical vapor deposition, and other advanced growth methods. Various physical and chemical propulsion mechanisms have been proposed to explain the motion behaviors including diffusiophoresis, bubble propulsion, interfacial tension gradients, and self-electrophoresis. The control and manipulation based upon external fields, catalytic alloys, and motion control through thermal modulation are discussed as well. Catalytic nanomotors represent an exciting technological challenge with the end goal being practical functional nanomachines that can perform a variety of tasks at the nanoscale.
引用
收藏
页码:25 / 39
页数:15
相关论文
共 58 条
[1]  
Alberts B., 2002, The shape and structure of proteins, Vfourth, DOI 10.1093/aob/mcg023
[2]   Thermal Modulation of Nanomotor Movement [J].
Balasubramanian, Shankar ;
Kagan, Daniel ;
Manesh, Kalayil Manian ;
Calvo-Marzal, Percy ;
Flechsig, Gerd-Uwe ;
Wang, Joseph .
SMALL, 2009, 5 (13) :1569-1574
[3]   Making molecular machines work [J].
Browne, Wesley R. ;
Feringa, Ben L. .
NATURE NANOTECHNOLOGY, 2006, 1 (01) :25-35
[4]   Synthetic nanomotors in microchannel networks: Directional microchip motion and controlled manipulation of cargo [J].
Burdick, Jared ;
Laocharoensuk, Rawiwan ;
Wheat, Philip M. ;
Posner, Jonathan D. ;
Wang, Joseph .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (26) :8164-+
[5]   Motility of ActA protein-coated microspheres driven by actin polymerization [J].
Cameron, LA ;
Footer, MJ ;
van Oudenaarden, A ;
Theriot, JA .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (09) :4908-4913
[6]   Directed rotational motion of microscale objects using interfacial tension gradients continually generated via catalytic reactions [J].
Catchmark, JM ;
Subramanian, S ;
Sen, A .
SMALL, 2005, 1 (02) :202-206
[7]   Ultrafast Catalytic Alloy Nanomotors [J].
Demirok, U. Korcan ;
Laocharoensuk, Rawiwan ;
Manesh, Kalayil Manian ;
Wang, Joseph .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (48) :9349-9351
[8]   Self-assembled autonomous runners and tumblers [J].
Ebbens, Stephen ;
Jones, Richard A. L. ;
Ryan, Anthony J. ;
Golestanian, Ramin ;
Howse, Jonathan R. .
PHYSICAL REVIEW E, 2010, 82 (01)
[9]   In pursuit of propulsion at the nanoscale [J].
Ebbens, Stephen J. ;
Howse, Jonathan R. .
SOFT MATTER, 2010, 6 (04) :726-738
[10]  
GAJEWSKI E, 1986, J BIOL CHEM, V261, P2733