Flexural Properties of Poly-L-Lactide and Polycaprolactone Shape Memory Composites Filled with Nanometer Calcium Carbonate

被引:10
作者
Liang, Ji-Zhao [1 ]
Duan, De-Rong [1 ]
Tang, Chak-Yin [2 ]
Tsui, Chi-Pong [2 ]
Chen, Da-Zhu [3 ]
机构
[1] S China Univ Technol, Sch Mech & Automot Engn, Res Div Green Funct Mat & Equipment, Guangzhou 510640, Guangdong, Peoples R China
[2] Hong Kong Polytech Univ, Dept Ind & Syst Engn, Hong Kong, Hong Kong, Peoples R China
[3] Shenzhen Univ, Dept Polymer Mat & Engn, Shenzhen, Peoples R China
来源
JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS | 2013年 / 52卷 / 07期
关键词
flexure modulus; flexure strength; nano-CaCO3; PCL; PLLA; shape memory composites; MELT FLOW BEHAVIOR; CAPILLARY EXTRUSION; BIO-COMPOSITES; BLENDS;
D O I
10.1080/00222348.2012.746572
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The flexural properties of poly-L-lactide (PLLA) and polycaprolactone (PCL) shape memory composites filled with nanometer calcium carbonate (nano-CaCO3) were determined at room temperature. The results showed that with the increase of the nano-CaCO3 weight fraction the flexural moduli and strength of PCL/nano-CaCO3 composites increased roughly linearly and reached a maximum at the filler content of 2%, while the flexural strength of the composites decreased. The flexural moduli and strength of the composites decreased roughly linearly with increasing PLLA/PCL ratio for the PLLA/PCL/nano-CaCO3 composites.
引用
收藏
页码:964 / 972
页数:9
相关论文
共 14 条
[1]   Shape-Memory Behavior of Poly(L-lactide)/Poly(ε-caprolactone) Blends [J].
Dong, Haiqing ;
Liu, Lijian ;
Li, Yongyong .
CHINA POSTDOCTORAL FORUM ON MATERIALS SCIENCE AND ENGINEERING, 2011, 266 :171-+
[2]   Impact Toughness and Flexural Properties of PPS/GF/Nano-CaCO3 Ternary Composites [J].
Liang, J. Z. .
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2008, 47 (12) :1227-1230
[3]   Melt flow behavior in capillary extrusion of nanosized calcium carbonate-filled poly(L-lactic acid) biocomposites [J].
Liang, Ji-Zhao ;
Tang, Chak-Yin ;
Zhou, Lin ;
Tsui, Chi-Pong ;
Li, Feng-Jiao .
POLYMER ENGINEERING AND SCIENCE, 2012, 52 (09) :1839-1844
[4]   Melt flow behavior in capillary extrusion of nanometer calcium carbonate filled PCL bio-composites [J].
Liang, Ji-Zhao ;
Zhou, Lin ;
Tang, Chak-Yin ;
Tsui, Chi-Pong ;
Li, Feng-Jiao .
POLYMER TESTING, 2012, 31 (01) :149-154
[5]   Melt density and flow property of PDLLA/nano-CaCO3 bio-composites [J].
Liang, Ji-Zhao ;
Tang, Chak-Yin ;
Zhou, Lin ;
He, Liu ;
Tsui, Chi-Pong .
COMPOSITES PART B-ENGINEERING, 2011, 42 (07) :1897-1900
[6]   Tensile and flexural properties of hollow glass bead-filled ABS composites [J].
Liang, JZ .
JOURNAL OF ELASTOMERS AND PLASTICS, 2005, 37 (04) :361-370
[7]   The Shape Memory Properties of Biodegradable Chitosan/Poly(L-lactide) Composites [J].
Meng, Qinghao ;
Hu, Jinlian ;
Ho, KaiChiu ;
Ji, Fenglong ;
Chen, Shaojun .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2009, 17 (03) :212-224
[8]  
Shen TF, 2011, ADV BIOM ENG, P302
[9]   Toughening Modification of PLLA/PBS Blends via In Situ Compatibilization [J].
Wang, Ruyin ;
Wang, Shifeng ;
Zhang, Yong ;
Wan, Chaoying ;
Ma, Piming .
POLYMER ENGINEERING AND SCIENCE, 2009, 49 (01) :26-33
[10]   A biodegradable shape-memory nanocomposite with excellent magnetism sensitivity [J].
Yu, Xiongjun ;
Zhou, Shaobing ;
Zheng, Xiaotong ;
Guo, Tao ;
Xiao, Yu ;
Song, Botao .
NANOTECHNOLOGY, 2009, 20 (23)