A series of isostructural mesoporous metal-organic frameworks obtained by ion-exchange induced single-crystal to single-crystal transformation

被引：127
作者：
Yao, Qingxia [1 ]
Sun, Junliang [1 ]
Li, Kuo [2 ]
Su, Jie [1 ]
Peskov, Maxim V. [1 ]
Zou, Xiaodong [1 ]
机构：
[1] Stockholm Univ, Dept Mat & Environm Chem, Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden
[2] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
来源：
DALTON TRANSACTIONS | 2012年 / 41卷 / 14期
基金：
瑞典研究理事会;
关键词：
SORPTION PROPERTIES; HYDROGEN STORAGE; SURFACE-AREA; GAS-UPTAKE; COORDINATION; CATENATION; CATALYSIS; SITES; PORES; MOFS;
D O I：
10.1039/c2dt12088g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of metal-organic frameworks representing a non-interpenetrated framework analogue of MOF-14 have been synthesized by using two different linkers, 4,4',4 ''-benzene-1,3,5-triyl-benzoic acid (H3BTB) and 4,4'-bipyridine (Bpy). Interestingly, the transition metal ions in the paddle-wheel metal clusters could be exchanged by other transition metal ions via a direct single-crystal to single-crystal transformation. This post-synthesis route can be used for synthesis of isomorphous metal-organic frameworks that cannot be obtained by direct synthesis.
引用
收藏
页码：3953 / 3955
页数：3
相关论文
共 37 条
  • [21] The modular synthesis of functional porous coordination networks
    Kawano, Masaki
    Kawamichi, Takehide
    Haneda, Tsuyoshi
    Kojima, Takahiro
    Fujita, Makoto
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (50) : 15418 - +
  • [22] A Mesoporous Metal-Organic Framework
    Klein, Nicole
    Senkovska, Irena
    Gedrich, Kristina
    Stoeck, Ulrich
    Henschel, Antje
    Mueller, Uwe
    Kaskel, Stefan
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (52) : 9954 - 9957
  • [23] Microporous pillared paddle-wheel frameworks based on mixed-ligand coordination of zinc ions
    Ma, BQ
    Mulfort, KL
    Hupp, JT
    [J]. INORGANIC CHEMISTRY, 2005, 44 (14) : 4912 - 4914
  • [24] Framework-catenation isomerism in metal-organic frameworks and its impact on hydrogen uptake
    Ma, Shengqian
    Sun, Daofeng
    Ambrogio, Michael
    Fillinger, Jacqueline A.
    Parkin, Sean
    Zhou, Hong-Cai
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (07) : 1858 - +
  • [25] Polymeric zinc ferrocenyl sulfonate as a molecular aspirator for the removal of toxic metal ions
    Mi, Liwei
    Hou, Hongwei
    Song, Zhiyong
    Han, Huayun
    Fan, Yaoting
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (06) : 1814 - 1821
  • [26] Rational construction of porous polymeric cadmium ferrocene-1,1′-disulfonates for transition metal ion exchange and sorption
    Mi, Liwei
    Hou, Hongwei
    Song, Zhiyong
    Han, Huayun
    Xu, Hong
    Fan, Yaoting
    Ng, Seik-Weng
    [J]. CRYSTAL GROWTH & DESIGN, 2007, 7 (12) : 2553 - 2561
  • [27] Chemical reduction of metal-organic framework materials as a method to enhance gas uptake and binding
    Mulfort, Karen L.
    Hupp, Joseph T.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (31) : 9604 - +
  • [28] Crystal structure and guest uptake of a mesoporous metal-organic framework containing cages of 3.9 and 4.7 nm in diameter
    Park, Young Kwan
    Choi, Sang Beom
    Kim, Hyunuk
    Kim, Kimoon
    Won, Byoung-Ho
    Choi, Kihang
    Choi, Jung-Sik
    Ahn, Wha-Seung
    Won, Nayoun
    Kim, Sungjee
    Jung, Dong Hyun
    Choi, Seung-Hoon
    Kim, Ghyung-Hwa
    Cha, Sun-Shin
    Jhon, Young Ho
    Yang, Jin Kuk
    Kim, Jaheon
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (43) : 8230 - 8233
  • [29] Dynamic channels of a porous coordination polymer responding to external stimuli
    Seki, K
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (10) : 1968 - 1971
  • [30] Shekhah O, 2009, NAT MATER, V8, P481, DOI [10.1038/NMAT2445, 10.1038/nmat2445]
1234